@article{oai:kutarr.kochi-tech.ac.jp:00000130, author = {Oka, Natsuhisa and Shimizu, Mamoru and Saigo, Kazuhiko and Wada, Takeshi}, issue = {15}, journal = {Tetrahedron}, month = {Apr}, note = {A novel phosphonium-type condensing reagent, 1,3-dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP), was designed and synthesized. A 31P NMR study on the condensation reactions of phosphate, alkylphosphonate, boranophosphate, and H-phosphonate derivatives with an alcohol in the presence of MNTP demonstrated the versatility and the enhanced activity of the new condensing reagent, compared to the previously reported phosphonium-type condensing reagents. The mechanism of the condensation reactions mediated by MNTP is discussed on the basis of the 31P NMR studies and theoretical calculations.}, pages = {3667--3673}, title = {1,3-Dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP): a powerful condensing reagent for phosphate and phosphonate esters}, volume = {62}, year = {2006} }