@article{oai:kutarr.kochi-tech.ac.jp:00000144, author = {Shimoda, M. and Konishi, T. and Tateishi, K. and Toujyou, T. and Tsukamoto, S. and Nishiwaki, N. and Arisawa, M. and Hoshiya, N. and Shuto, S. and Isomura, N. and Yokota, H. and Furukawa, Y. and Iizuka, K. and Ogiwara, T. and Isozaki, Y. and Yamashita, Y. and Yoshikawa, H. and Ueda, S. and Kobayashi, K.}, issue = {2}, journal = {Journal of Applied Physics}, month = {Jul}, note = {We present studies on the structure and chemical states of a catalyst developed by immobilizing palladium on S-terminated GaAs(001). Hard x-ray photoelectron spectroscopy (HX-PES) of core-level and valence band photoemission consistently indicates that the organopalladium molecules are reduced on the surface yielding Pd nanoparticles with a metallic nature. This finding is supported by high-resolution observations using scanning electron microscopy and backscattered electron image. HX-PES results also reveal that a portion of S atoms forming the S-termination is oxidized during the formation of Pd nanoparticles.}, pages = {024309-1--024309-5}, title = {Hard x-ray photoemission spectroscopic investigation of palladium catalysts immobilized on a GaAs(001) surface}, volume = {108}, year = {2009} }