{"created":"2023-05-15T12:35:14.958015+00:00","id":164,"links":{},"metadata":{"_buckets":{"deposit":"aed7cb46-2b78-41a3-8954-04fdc5c3ef11"},"_deposit":{"created_by":2,"id":"164","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"164"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000164","sets":["5"]},"author_link":["619","618","617"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-12-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"50","bibliographicPageEnd":"8760","bibliographicPageStart":"8757","bibliographicVolumeNumber":"46","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Fourteen isomers of bis(formylmethano)C60 were isolated and characterized. A mixture of the bisadducts was obtained by the reaction of C60 with an α-formylsulfonium ylide, and then separated into fifteen fractions by preparative HPLC, preparative TLC, and recycling preparative HPLC. Fourteen of fifteen fractions were found to consist of a single isomer, respectively, which were assigned to the trans-2 (3 diastereo-isomers), trans-3 (3 diastereo-isomers), trans-4 (3 diastereo-isomers), equarorial (2 diastereo-isomers), and cis-2 (3 diastereo-isomers) bisadducts by the comparison of their UV/vis spectra with those of the bisadducts obtained by the Bingel-Hirsch reaction. The 1H- and 13C-NMR analysis, the transformation of the formyl groups, and the dipole moment calculation clarified the stereochemistry of the subsitutents on the two cyclopropane bridge-head carbons (in/in, in/out, and out/out)","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tetlet.2005.10.027","subitem_relation_type_select":"DOI"}}]},"item_2_relation_44":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://www.sciencedirect.com/science/journal/00404039"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.sciencedirect.com/science/journal/00404039","subitem_relation_type_select":"URI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2005 Elsevier Ltd. All rights reserved."}]},"item_2_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00861801@@@AA11539822","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4039","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ito, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"617","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishida, Yasuhiro"}],"nameIdentifiers":[{"nameIdentifier":"618","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{"nameIdentifier":"619","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"TetL_46_50_8757.pdf","filesize":[{"value":"559.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TetL_46_50_8757.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/164/files/TetL_46_50_8757.pdf"},"version_id":"bbb826ed-107e-423d-91d7-bb39f5809d48"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"bifunctionalization","subitem_subject_scheme":"Other"},{"subitem_subject":"diastereo-isomer","subitem_subject_scheme":"Other"},{"subitem_subject":"α-formylsulfonium ylide","subitem_subject_scheme":"Other"},{"subitem_subject":"fullerene","subitem_subject_scheme":"Other"},{"subitem_subject":"regio-isomer","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-01-28"},"publish_date":"2012-01-28","publish_status":"0","recid":"164","relation_version_is_last":true,"title":["Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:42:55.816338+00:00"}