{"created":"2023-05-15T12:35:16.547818+00:00","id":191,"links":{},"metadata":{"_buckets":{"deposit":"e6888357-851e-4bac-9658-89e86ccc329a"},"_deposit":{"created_by":2,"id":"191","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"191"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000191","sets":["5"]},"author_link":["757","759","756","755","754","760","758","753","752"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-02","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"183","bibliographicPageStart":"178","bibliographicVolumeNumber":"62","bibliographic_titles":[{"bibliographic_title":"The Journal of Supercritical Fluids"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Simple treatment of conjugated all E-dienal, (2E,4E)-hexa-2,4-dienal, in subcritical water afforded an intramolecular redox product, non-conjugated Z-enoic acid, (Z)-hex-3-enoic acid, in 42% yield without the usage of a metal catalyst in one-step under the conditions of 250 ℃, 10 min, and 0.35 g mL^<-1> water amount. Similar treatment of the dienal in superheated benzyl alcohol produced corresponding ester, benzyl (Z)-hex-3-enoate, in 34% yield under the conditions of 300 °C, 30 min, and 0.5 g mL^<-1> benzyl alcohol amount. The obtained (Z)-hex-3-enoic acid was transformed to cis-β-hydroxy-γ-ethyl-γ-lactone in 90% yield by hydrogen peroxide at 60 °C for one day under solvent-free conditions.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.supflu.2011.10.022","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0896-8446","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Chen, Xin"}],"nameIdentifiers":[{"nameIdentifier":"752","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sumoto, Kana"}],"nameIdentifiers":[{"nameIdentifier":"753","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mitani, Sotatsu"}],"nameIdentifiers":[{"nameIdentifier":"754","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamagami, Tetsuya"}],"nameIdentifiers":[{"nameIdentifier":"755","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yokoyama, Kazuya"}],"nameIdentifiers":[{"nameIdentifier":"756","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Wang, Pengyu"}],"nameIdentifiers":[{"nameIdentifier":"757","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hirao, Shotaro"}],"nameIdentifiers":[{"nameIdentifier":"758","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{"nameIdentifier":"759","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kobiro, Kazuya"}],"nameIdentifiers":[{"nameIdentifier":"760","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"JSF_62_178.pdf","filesize":[{"value":"238.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JSF_62_178.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/191/files/JSF_62_178.pdf"},"version_id":"3a4748f4-74d0-4639-968b-c7817ff25763"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-03-29"},"publish_date":"2013-03-29","publish_status":"0","recid":"191","relation_version_is_last":true,"title":["One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:42:11.854392+00:00"}