{"created":"2023-05-15T12:35:16.767520+00:00","id":194,"links":{},"metadata":{"_buckets":{"deposit":"b139c1a8-3602-4224-af35-3bc98e0820f9"},"_deposit":{"created_by":2,"id":"194","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"194"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000194","sets":["5"]},"author_link":["769","768","767"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1905-06-23","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"14","bibliographicPageStart":"13","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"Nucleic Acids Research Supplement"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Diastereopure nucleoside 3′-cyclic phosphoramidites were synthesized stereoselectively from enantiopure 1,2-amino alcohols. In the presence of a novel activator, these phosphoramidites underwent the condensation with 3′-O-tert-butyldimethylsilylthymidine to give the corresponding phosphite intermediates. Upon sulfurization, followed by deprotection, dithymidine phosphorothioate was obtained in good yield with good to excellent diastereoselectivity.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Oxford University Press"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1093/nass/1.1.13","subitem_relation_type_select":"DOI"}}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"http://nass.oxfordjournals.org/content/1/1/13 | http://nass.oxfordjournals.org/content/1/1/13"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0261-3166","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Oka, Natsuhisa"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wada, Takeshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"NARS_1_1_13.pdf","filesize":[{"value":"141.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"NARS_1_1_13.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/194/files/NARS_1_1_13.pdf"},"version_id":"339ee27c-de2a-43a1-94af-6cff29a10627"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stereoselective synthesis of dinucleoside phosphorothioate using enantiopure 1,2-amino alcohols as chiral auxiliaries","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stereoselective synthesis of dinucleoside phosphorothioate using enantiopure 1,2-amino alcohols as chiral auxiliaries"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-03-29"},"publish_date":"2013-03-29","publish_status":"0","recid":"194","relation_version_is_last":true,"title":["Stereoselective synthesis of dinucleoside phosphorothioate using enantiopure 1,2-amino alcohols as chiral auxiliaries"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:42:05.679043+00:00"}