@article{oai:kutarr.kochi-tech.ac.jp:00000198, author = {Nishiwaki, Nagatoshi and Hirao, Shotaro and Sawayama, Jun and Saigo, Kazuhiko}, issue = {1}, journal = {Heterocycles}, month = {Jul}, note = {Nitromalonaldehyde (NMA-H) is one of useful synthons for synthesizing nitro compounds. However, NMA-H itself cannot be practically employed because of its unstable property. Therefore, sodium salt of NMA-H (NMA-Na) has been used as its synthetic equivalent from old time, and NMA-Na is still important even now albeit several restrictions with regard to safety and treatability. On the other hand, dinitropyridone, nitropyrimidinone and dinitropyrazole can be employed in place of NMA-Na for the same purpose, and furthermore azadienamines, formylnitroenamines and dinitropyrazole also serve as the synthetic equivalents of NMA-H, which are usable in common organic solvents with safety. These reagents condense with dinucleophiles to afford various kinds of nitro compounds.}, pages = {115--134}, title = {Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles}, volume = {84}, year = {2011} }