{"created":"2023-05-15T12:35:17.058260+00:00","id":198,"links":{},"metadata":{"_buckets":{"deposit":"bde439df-bde6-4ae9-bd3b-0186f1749efa"},"_deposit":{"created_by":2,"id":"198","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"198"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000198","sets":["5"]},"author_link":["786","785","788","787"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011-07-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"134","bibliographicPageStart":"115","bibliographicVolumeNumber":"84","bibliographic_titles":[{"bibliographic_title":"Heterocycles"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Nitromalonaldehyde (NMA-H) is one of useful synthons for synthesizing nitro compounds. However, NMA-H itself cannot be practically employed because of its unstable property. Therefore, sodium salt of NMA-H (NMA-Na) has been used as its synthetic equivalent from old time, and NMA-Na is still important even now albeit several restrictions with regard to safety and treatability. On the other hand, dinitropyridone, nitropyrimidinone and dinitropyrazole can be employed in place of NMA-Na for the same purpose, and furthermore azadienamines, formylnitroenamines and dinitropyrazole also serve as the synthetic equivalents of NMA-H, which are usable in common organic solvents with safety. These reagents condense with dinucleophiles to afford various kinds of nitro compounds.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Japan Institute of Heterocyclic Chemistry"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/REV-11-SR(P)3","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hirao, Shotaro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sawayama, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"Heterocycles_84_1_115.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Heterocycles_84_1_115.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/198/files/Heterocycles_84_1_115.pdf"},"version_id":"9c367ffa-716d-41f4-9e21-6521ce582a15"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-03-29"},"publish_date":"2013-03-29","publish_status":"0","recid":"198","relation_version_is_last":true,"title":["Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:42:00.855625+00:00"}