@article{oai:kutarr.kochi-tech.ac.jp:00000206,
 author = {Ikuma, Naohiko and Sumioka, Satoko and Asahara, Haruyasu and Oshima, Takumi},
 issue = {28},
 journal = {Tetrahedron Letters},
 month = {},
 note = {The mCPBA oxidation of methano-bridged [5,6] open fulleroid 1 anomalously resulted in the selective electrophilic addition at the bridgehead anti-Bredt double bond rather than the usual epoxidation. The mechanistic preference for the unprecedented stepwise addition of mCPBA vs the concerted epoxidation was explained in terms of the notable π-orbital misalignment (>30°) based on the B3LYP/6-31G(d) level calculation.},
 pages = {3581--3584},
 title = {Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid},
 volume = {53},
 year = {2012}
}