{"created":"2023-05-15T12:35:17.653089+00:00","id":206,"links":{},"metadata":{"_buckets":{"deposit":"746763c7-9fc7-4f19-bc3c-ef96bcb0e5aa"},"_deposit":{"created_by":2,"id":"206","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"206"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000206","sets":["5"]},"author_link":["813","810","811","812"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"28","bibliographicPageEnd":"3584","bibliographicPageStart":"3581","bibliographicVolumeNumber":"53","bibliographic_titles":[{"bibliographic_title":"Tetrahedron Letters"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The mCPBA oxidation of methano-bridged [5,6] open fulleroid 1 anomalously resulted in the selective electrophilic addition at the bridgehead anti-Bredt double bond rather than the usual epoxidation. The mechanistic preference for the unprecedented stepwise addition of mCPBA vs the concerted epoxidation was explained in terms of the notable π-orbital misalignment (>30°) based on the B3LYP/6-31G(d) level calculation.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd."}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tetlet.2012.05.007","subitem_relation_type_select":"DOI"}}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ikuma, Naohiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sumioka, Satoko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Asahara, Haruyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Oshima, Takumi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"27-41.pdf","filesize":[{"value":"512.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"27-41.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/206/files/27-41.pdf"},"version_id":"ff034acd-739f-49ba-a344-47fb6e238a63"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-03-25"},"publish_date":"2016-03-25","publish_status":"0","recid":"206","relation_version_is_last":true,"title":["Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:41:47.896576+00:00"}