@article{oai:kutarr.kochi-tech.ac.jp:00000215, author = {Nishiwaki, Nagatoshi and Kamimura, Ryuichiro and Shono, Kimihiro and Kawakami, Toshihiko and Nakayama, Katsuhisa and Nishino, Kohei and Nakayama, Takayuki and Takahashi, Keisuke and Nakamura, Aki and Hosokawa, Takahiro}, issue = {27}, journal = {Tetrahedron Letters}, month = {}, note = {A novel catalyst system of Pd(OAc)2-HFIP induces double-bond migration of allylbenzenes under mild conditions with low catalytic loading to afford 1-propenylbenzenes. The reaction shows unique substituent effect that is highly dependent on the distance of substituents from the allylic moiety. Thus, the reactivity of substrates bearing a methyl group is ordered in para > meta > ortho, whereas it is entirely reversed as ortho > meta > para for methoxy and chloro substituents.}, pages = {3590--3592}, title = {Efficient double bond migration of allylbenzenes catalyzed by Pd(OAc)_2-HFIP system with unique substituent effect}, volume = {51}, year = {2010} }