{"created":"2023-05-15T12:35:18.873719+00:00","id":224,"links":{},"metadata":{"_buckets":{"deposit":"586b87a0-e8c1-482b-a264-21ef77381b80"},"_deposit":{"created_by":2,"id":"224","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"224"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000224","sets":["5"]},"author_link":["888","889","890","891","893","884","886","892","887","885"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"8","bibliographicPageEnd":"2839","bibliographicPageStart":"2832","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"Organic & Biomolecular Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A nitrile oxide containing a carbamoyl group is readily generated upon the treatment of 2-methyl-4-nitro-3-isoxazolin-5(2H)-one with water under mild reaction conditions, even in the absence of special reagents. The obtained nitrile oxide undergoes cycloaddition with dipolarophiles, alkynes and alkenes, to afford the corresponding isoxazol(in)es, which are useful intermediates in the synthesis of polyfunctionalized compounds. A plausible mechanism underlying the formation of the nitrile oxide is proposed, which involves an anomalous hydration/dehydration sequence. DFT calculations were also performed to support this mechanism.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/C0OB01005G","subitem_relation_type_select":"DOI"}}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"http://pubs.rsc.org/en/content/articlelanding/2011/ob/c0ob01005g#!divAbstract | http://pubs.rsc.org/en/content/articlelanding/2011/ob/c0ob01005g#!divAbstract"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kobiro, Kazuya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kiyoto, Hideyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hirao, Shotaro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sawayama, Jun"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okajima, Yoshikazu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Uehara, Toshiharu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maki, Asaka"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ariga, Masahiro"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"27-16.pdf","filesize":[{"value":"214.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"27-16.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/224/files/27-16.pdf"},"version_id":"9ca719d0-97d2-448a-9c4b-d597d53e2d7f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"An anomalous hydration/dehydration sequence for the mild generation of a nitrile oxide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"An anomalous hydration/dehydration sequence for the mild generation of a nitrile oxide"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-03-25"},"publish_date":"2016-03-25","publish_status":"0","recid":"224","relation_version_is_last":true,"title":["An anomalous hydration/dehydration sequence for the mild generation of a nitrile oxide"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:41:14.142818+00:00"}