{"created":"2023-05-15T12:35:19.213252+00:00","id":229,"links":{},"metadata":{"_buckets":{"deposit":"a0be8db9-2786-4e33-b1fd-3aac20aba2d5"},"_deposit":{"created_by":2,"id":"229","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"229"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000229","sets":["5"]},"author_link":["916","911","917","913","908","918","922","914","909","915","921","923","910","920","912","919"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2011","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"407","bibliographicPageStart":"405","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Physica Status Solidi (C)"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Organopalladium species ({Pd}) immobilized on an Sterminated GaAs substrate (S/GaAs) effectively catalyzes C-C bond formation in the Mizoroki-Heck reaction with cycle durability. However, the immobilizing mechanism of {Pd} is unknown. In this study, we deposited Pd(OCOCH3)2 on S/GaAs in two different methods, namely dry-physical vapor-deposition and wetchemical deposition, and compared the catalytic activities in the Mizoroki-Heck reaction. Also, S-termination and {Pd}-immobilization on GaAs grains were performed by the wet-chemical method to monitor the change in the surface chemical structure during the preparation process with diffuse reflectance Fourier transform infrared spectroscopy (FT-IR). FT-IR measurements implied that the immobilization of catalytic active {Pd} was related to the OH groups on the S-terminated surface. {Pd}-S/GaAs prepared dryphysically showed poor catalytic activity, because {Pd} was not immobilized under absence of OH groups.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"WILEY-VCH Verlag GmbH"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/pssc.201000436","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the accepted version of the following article: Konishi, T., Nishiwaki, N., Toujyou, T., Ishikawa, T., Teraoka, T., Ueta, Y., Kihara, Y., Moritoki, H., Tono, T., Musashi, M., Tada, T., Fujikawa, S., Takahasi, M., Bell, G., Shimoda, M. and Tsukamoto, S. (2011), Surface study of organopalladium molecules on S-terminated GaAs. Phys. Status Solidi C, 8: 405-407, which has been published in final form at http://dx.doi.org/10.1002/pssc.201000436"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Konishi, Tomoya"}],"nameIdentifiers":[{"nameIdentifier":"908","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{"nameIdentifier":"909","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Toujyou, Takashi"}],"nameIdentifiers":[{"nameIdentifier":"910","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ishikawa, Takuma"}],"nameIdentifiers":[{"nameIdentifier":"911","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Teraoka, Teruki"}],"nameIdentifiers":[{"nameIdentifier":"912","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ueta, Yukiko"}],"nameIdentifiers":[{"nameIdentifier":"913","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kihara, Yoshifumi"}],"nameIdentifiers":[{"nameIdentifier":"914","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Moritoki, Hideji"}],"nameIdentifiers":[{"nameIdentifier":"915","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tono, Tatsuo"}],"nameIdentifiers":[{"nameIdentifier":"916","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Musashi, Mio"}],"nameIdentifiers":[{"nameIdentifier":"917","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tada, Takashi"}],"nameIdentifiers":[{"nameIdentifier":"918","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fujikawa, Seiji"}],"nameIdentifiers":[{"nameIdentifier":"919","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takahasi, Masamitu"}],"nameIdentifiers":[{"nameIdentifier":"920","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Bell, Gavin"}],"nameIdentifiers":[{"nameIdentifier":"921","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Shimoda, Masahiko"}],"nameIdentifiers":[{"nameIdentifier":"922","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tsukamoto, Shiro"}],"nameIdentifiers":[{"nameIdentifier":"923","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"27-15.pdf","filesize":[{"value":"116.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"27-15.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/229/files/27-15.pdf"},"version_id":"b296f9a3-7498-4166-bd25-7c32a4298098"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Surface study of organopalladium molecules on S-terminated GaAs","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Surface study of organopalladium molecules on S-terminated GaAs"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-03-25"},"publish_date":"2016-03-25","publish_status":"0","recid":"229","relation_version_is_last":true,"title":["Surface study of organopalladium molecules on S-terminated GaAs"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:41:04.845569+00:00"}