{"created":"2023-05-15T12:35:19.721491+00:00","id":236,"links":{},"metadata":{"_buckets":{"deposit":"6b899eb1-9324-42a7-b090-3f29e28ac68a"},"_deposit":{"created_by":2,"id":"236","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"236"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000236","sets":["5"]},"author_link":["982","975","981","979","980","976","977","978"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"1991","bibliographicPageStart":"1987","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"Organic & Biomolecular Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new protocol for synthesizing different functionalized isoxazoles is provided. Carbamoylnitrile oxide generated from nitroisoxazolone underwent inverse electron-demand 1,3-dipolar cycloaddition with 1,3-dicarbonyl compounds in the presence of magnesium acetate that formed magnesium enolatein situ. Although electron-deficient trifluoroacetoacetate did not undergo this cycloaddition under the same conditions, conversion to sodium enolate furnish the corresponding bis-functionalized trifluoromethylisoxazole. The DFT calculations using B3LYP 6-31G+(d,p) also supported the aforementioned reactivity.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Royal Society of Chemistry"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1039/C2OB06925C","subitem_relation_type_select":"DOI"}}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"http://pubs.rsc.org/en/content/articlelanding/2012/ob/c2ob06925c#!divAbstract | http://pubs.rsc.org/en/content/articlelanding/2012/ob/c2ob06925c#!divAbstract"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{"nameIdentifier":"975","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kobiro, Kazuya"}],"nameIdentifiers":[{"nameIdentifier":"976","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hirao, Shotaro"}],"nameIdentifiers":[{"nameIdentifier":"977","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sawayama, Jun"}],"nameIdentifiers":[{"nameIdentifier":"978","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{"nameIdentifier":"979","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ise, Yumiko"}],"nameIdentifiers":[{"nameIdentifier":"980","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishizawa, Maho"}],"nameIdentifiers":[{"nameIdentifier":"981","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ariga, Masahiro"}],"nameIdentifiers":[{"nameIdentifier":"982","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"27-21.pdf","filesize":[{"value":"201.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"27-21.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/236/files/27-21.pdf"},"version_id":"0335252e-91e6-4858-b028-9ed37d6a4ea4"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-03-25"},"publish_date":"2016-03-25","publish_status":"0","recid":"236","relation_version_is_last":true,"title":["One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:40:50.981478+00:00"}