{"created":"2023-05-15T12:35:21.383495+00:00","id":260,"links":{},"metadata":{"_buckets":{"deposit":"2515b39e-0573-4371-a3d9-3d07979d10f3"},"_deposit":{"created_by":2,"id":"260","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"260"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000260","sets":["5"]},"author_link":["1068","1069","1067"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-07","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1245","bibliographicPageStart":"1241","bibliographicVolumeNumber":"11","bibliographic_titles":[{"bibliographic_title":"Beilstein Journal of Organic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"N-Methylated amides (N,4-dimethylbenzamide and N-methylcyclohexanecarboxamide) were systematically subjected to chemical transformations, namely, N-tosylation followed by nucleophilic substitution. The amide function was converted to the corresponding carboxylic acid, esters, amides, aldehyde, and ketone upon treatment with hydroxide, alkoxide, amine, diisobutylaluminium hydride and Grignard reagent, respectively. In these transformations, N-methyl-N-tosylcarboxamides behave like a Weinreb amide. Similarly, N-methyl-5-phenylisoxazole-3-carboxamide was converted into 3-functionalized isoxazole derivatives. Since the amide was prepared by the cycloaddition reaction of ethynylbenzene and N-methylcarbamoylnitrile oxide, the nitrile oxide served as the equivalent of the nitrile oxides bearing a variety of functional groups such as carboxy, alkoxycarbonyl, carbamoyl, acyl and formyl moieties.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Beilstein-Institut"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3762/bjoc.11.138","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2015 Asahara et al; licensee Beilstein-Institut."},{"subitem_rights":"This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited."},{"subitem_rights":"The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)"}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"https://creativecommons.org/licenses/by/2.0/ | https://creativecommons.org/licenses/by/2.0/"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Asahara, Haruyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Arikiyo, Keita"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-46.pdf","filesize":[{"value":"251.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-46.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/260/files/28-46.pdf"},"version_id":"fd50e668-4de5-461e-98da-b86394539c09"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"acylnitrile oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"amide","subitem_subject_scheme":"Other"},{"subitem_subject":"formylnitrile oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"functionalized nitrile oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"Weinreb amide","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Development of variously functionalized nitrile oxides","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Development of variously functionalized nitrile oxides"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"260","relation_version_is_last":true,"title":["Development of variously functionalized nitrile oxides"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:40:05.507365+00:00"}