{"created":"2023-05-15T12:35:21.877884+00:00","id":269,"links":{},"metadata":{"_buckets":{"deposit":"6288cae0-646c-417f-b44b-ffb3b1b1d7c7"},"_deposit":{"created_by":2,"id":"269","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"269"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000269","sets":["5"]},"author_link":["1155","1160","1159","1156","1157","1158"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6","bibliographicPageEnd":"1431","bibliographicPageStart":"1421","bibliographicVolumeNumber":"71","bibliographic_titles":[{"bibliographic_title":"Polymer Bulletin"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer Berlin Heidelberg"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1007/s00289-014-1132-3","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"The final publication is available at link.springer.com"}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"http://dx.doi.org/10.1007/s00289-014-1132-3 | http://dx.doi.org/10.1007/s00289-014-1132-3"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0170-0839","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sugimoto, Ryuichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kaneko, Hideyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saito, Junji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawahara, Nobuo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsuo, Shingo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Matsugi, Tomoaki"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-15.pdf","filesize":[{"value":"446.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-15.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/269/files/28-15.pdf"},"version_id":"718637ad-89e9-476c-8877-c7cc39a15197"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Atom transfer radical polymerization (ATRP)","subitem_subject_scheme":"Other"},{"subitem_subject":"Functionalization of polymers","subitem_subject_scheme":"Other"},{"subitem_subject":"Graft polymers","subitem_subject_scheme":"Other"},{"subitem_subject":"Halogenated","subitem_subject_scheme":"Other"},{"subitem_subject":"Polyolefin","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"269","relation_version_is_last":true,"title":["Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:39:49.533136+00:00"}