@article{oai:kutarr.kochi-tech.ac.jp:00000284, author = {Asahara, Haruyasu and Kataoka, Asuka and Hirao, Shotaro and Nishiwaki, Nagatoshi}, issue = {18}, journal = {European Journal of Organic Chemistry}, month = {Jun}, note = {A new strategy for synthesis of the 2-pyridyl carbamates is reported. This strategy exploits a new intramolecular transformation of an acyloxy group from N-carbamoyloxypyridinium salts (Reissert-Henze-type reaction) as the key step. Addition of a silver salt effectively accelerates the intramolecular attack of the carbonyl oxygen at the 2-position of the pyridine ring. Additionally, a new rearrangement of the acyloxy group, combined with insertion of an ethereal solvent to give pyridine derivatives having a coordinating tether, is reported.}, pages = {3994--3999}, title = {Functionalization of a Pyridine Framework through Intramolecular Reissert-Henze Reaction of N-(Carbamoyloxy)pyridinium Salts and Unexpected Insertion of Ethereal Solvents}, volume = {2015}, year = {2015} }