{"created":"2023-05-15T12:35:23.285217+00:00","id":293,"links":{},"metadata":{"_buckets":{"deposit":"436d7524-c005-47b7-b080-49983e28a391"},"_deposit":{"created_by":2,"id":"293","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"293"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000293","sets":["5"]},"author_link":["1312","1310","1314","1311","1313","1315"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"302","bibliographicPageStart":"297","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"Asian Journal of Organic Chemistry"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"2-Arylated-5-nitropyridines were efficiently synthesized by a three-component ring transformation of 3,5-dinitro-2-pyridone with aromatic ketones in the presence of ammonium acetate, in which the dinitropyridone serves as a synthetic equivalent of an unstable nitromalonaldehyde. Although a 2,8-diazabicyclo[3.3.1]non-3-ene derivative was also formed as a byproduct, it was converted into nitropyridines under the reaction conditions, heating in the presence of ammonium acetate. This experimental fact implies that the former compound is a kinetically controlled product and the latter is a thermodynamically controlled product because of the aromatization. This method is applicable to various kinds of aryl and (hetero)aryl ketones to afford the corresponding (hetero)arylated pyridines in good to excellent yields.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"John Wiley & Sons"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/ajoc.201300282","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the accepted version of the following article: Corrigendum: Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone Volume 4, Issue 2, 94, Article first published online: 2 February 2015, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201300282/abstract;jsessionid=660535A8C8D3756DDD98C38F7A495083.f04t03?systemMessage=Pay+per+view+article+purchase%28PPV%29+on+Wiley+Online+Library+will+be+unavailable+on+Saturday+11th+March+from+05%3A00-14%3A00+GMT+%2F+12%3A00-09%3A00+EST+%2F+13%3A00-22%3A00+SGT+for+essential+maintenance.++Apologies+for+the+inconvenience.. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy."}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2193-5807","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Le, Thi Song"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Asahara, Haruyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kobiro, Kazuya"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Sugimoto, Ryuichi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-12.pdf","filesize":[{"value":"422.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-12.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/293/files/28-12.pdf"},"version_id":"1a6c4e21-dd70-4fdc-b58b-7ae22c86f8cf"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Biaryls","subitem_subject_scheme":"Other"},{"subitem_subject":"Multicomponent reactions","subitem_subject_scheme":"Other"},{"subitem_subject":"Nitrogen heterocycles","subitem_subject_scheme":"Other"},{"subitem_subject":"Nitropyridines","subitem_subject_scheme":"Other"},{"subitem_subject":"Ring transformation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"293","relation_version_is_last":true,"title":["Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:39:07.951947+00:00"}