{"created":"2023-05-15T12:35:23.354848+00:00","id":294,"links":{},"metadata":{"_buckets":{"deposit":"3cbafc32-ec27-44a0-ba0b-dba359398840"},"_deposit":{"created_by":2,"id":"294","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"294"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000294","sets":["5"]},"author_link":["1319","1317","1321","1318","1320","1316"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"619","bibliographicPageStart":"614","bibliographicVolumeNumber":"26","bibliographic_titles":[{"bibliographic_title":"Chirality"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An improved method, which is highly reproducible, was developed for the enantioseparation of racemic O-ethyl phenylphosphonothioic acid (1a) with brucine by introducing seeding to a supersaturated solution of the diastereomeric salt mixture. The present method gave both diastereomeric salts in high yields with a diastereomeric ratio of >99.5:0.5 upon choosing the crystallization solvent (MeOH for the (R)-1a salt and MeOH/H_2O for the (S)-1a salt). The enantiopure acid 1a showed a good chirality recognition ability for not only strong bases, such as amines and amino alcohols, but also weakly basic alcohols and was applicable as a solvating agent to the ^1H NMR determination of the enantiomeric excess of chiral amines, amino alcohols, and alcohols, including aliphatic substrates.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"John Wiley & Sons, Inc."}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/chir.22315","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Chirality 26:614-619, 2014. © 2014 Wiley Periodicals, Inc., which has been published in final form at http://dx.doi.org/10.1002/chir.22315. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1520-636X","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsumoto, Kazushige"}],"nameIdentifiers":[{"nameIdentifier":"1316","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sawayama, Jun"}],"nameIdentifiers":[{"nameIdentifier":"1317","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hirao, Shotaro"}],"nameIdentifiers":[{"nameIdentifier":"1318","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{"nameIdentifier":"1319","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sugimoto, Ryuichi"}],"nameIdentifiers":[{"nameIdentifier":"1320","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Saigo, Kazuhiko"}],"nameIdentifiers":[{"nameIdentifier":"1321","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-43.pdf","filesize":[{"value":"385.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-43.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/294/files/28-43.pdf"},"version_id":"943dce6e-a0a3-4781-9718-0c69e152cea2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"294","relation_version_is_last":true,"title":["Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:39:05.458177+00:00"}