{"created":"2023-05-15T12:35:23.750040+00:00","id":301,"links":{},"metadata":{"_buckets":{"deposit":"87a8e7b6-706a-486e-af86-b00dacb7812e"},"_deposit":{"created_by":2,"id":"301","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"301"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000301","sets":["5"]},"author_link":["1352","1350","1351"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"37","bibliographicPageEnd":"6528","bibliographicPageStart":"6522","bibliographicVolumeNumber":"70","bibliographic_titles":[{"bibliographic_title":"Tetrahedron"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A practical, convenient, and safe cyano(nitro)methylation method was developed, in which cyano-aci-nitroacetate served as a synthetic equivalent of anionic nitroacetonitrile. A control of the single/double Michael additions was achieved, which enabled the synthesis of unsymmetrical double Michael adducts. Moreover, the Michael adducts can be used as precursors of pyridine and naphthyridine frameworks.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier Ltd."}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.tet.2014.07.013","subitem_relation_type_select":"DOI"}}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0040-4020","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Asahara, Haruyasu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Muto, Kyo"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-40.pdf","filesize":[{"value":"605.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-40.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/301/files/28-40.pdf"},"version_id":"2b106d19-917f-4ee6-82e2-0e81c8a57607"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Nitroacetonitrile","subitem_subject_scheme":"Other"},{"subitem_subject":"Michael addition","subitem_subject_scheme":"Other"},{"subitem_subject":"Pyridine","subitem_subject_scheme":"Other"},{"subitem_subject":"[1,8]-Naphthyridine","subitem_subject_scheme":"Other"},{"subitem_subject":"Polyfunctionalized compound","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Safe cyano(nitro)methylating reagent—Michael addition of cyano-aci-nitroacetate leading to δ-functionalized α-nitronitriles","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Safe cyano(nitro)methylating reagent—Michael addition of cyano-aci-nitroacetate leading to δ-functionalized α-nitronitriles"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"301","relation_version_is_last":true,"title":["Safe cyano(nitro)methylating reagent—Michael addition of cyano-aci-nitroacetate leading to δ-functionalized α-nitronitriles"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:38:52.276681+00:00"}