{"created":"2023-05-15T12:35:23.982035+00:00","id":306,"links":{},"metadata":{"_buckets":{"deposit":"892b0992-20b2-44c3-a7aa-4ce4329d76c1"},"_deposit":{"created_by":2,"id":"306","owners":[2],"pid":{"revision_id":0,"type":"depid","value":"306"},"status":"published"},"_oai":{"id":"oai:kutarr.kochi-tech.ac.jp:00000306","sets":["5"]},"author_link":["1367","1365","1368","1366"],"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"827-11","bibliographicPageStart":"827-1","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"Molecules"}]}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A metal-free, mild and efficient method for the synthesis of 2-methylquinolines was successfully developed by condensation of anilines with vinyl ethers in the presence of catalytic amount of iodine. Modification of both pyridine and benzene moieties was easily achieved by changing only the vinyl ether and aniline. In this reaction, the iodine species was revealed to show dual behavior; molecular iodine serves as an oxidant, while its reduced form, hydrogen iodide, activates the vinyl ether. The redox reaction between these iodine species enables the use of a catalytic amount of iodine in this synthetic method.","subitem_description_type":"Abstract"}]},"item_2_publisher_35":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI"}]},"item_2_relation_13":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3390/molecules21070827","subitem_relation_type_select":"DOI"}}]},"item_2_rights_14":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0)."}]},"item_2_rights_15":{"attribute_name":"権利（URI）","attribute_value_mlt":[{"subitem_rights":"https://creativecommons.org/licenses/by/4.0/ | https://creativecommons.org/licenses/by/4.0/"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1420-3049","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_18":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Le, Song Thi"}],"nameIdentifiers":[{"nameIdentifier":"1365","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yasuoka, Chisa"}],"nameIdentifiers":[{"nameIdentifier":"1366","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Asahara, Haruyasu"}],"nameIdentifiers":[{"nameIdentifier":"1367","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Nishiwaki, Nagatoshi"}],"nameIdentifiers":[{"nameIdentifier":"1368","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-02-13"}],"displaytype":"detail","filename":"28-47.pdf","filesize":[{"value":"6.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"28-47.pdf","url":"https://kutarr.kochi-tech.ac.jp/record/306/files/28-47.pdf"},"version_id":"d5112e6b-5da4-4467-8d6d-9be780b62d12"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"2-methylquinoline","subitem_subject_scheme":"Other"},{"subitem_subject":"iodine-mediated reaction","subitem_subject_scheme":"Other"},{"subitem_subject":"aniline","subitem_subject_scheme":"Other"},{"subitem_subject":"vinyl ether","subitem_subject_scheme":"Other"},{"subitem_subject":"redox reaction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines"}]},"item_type_id":"2","owner":"2","path":["5"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-03-24"},"publish_date":"2017-03-24","publish_status":"0","recid":"306","relation_version_is_last":true,"title":["Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines"],"weko_creator_id":"2","weko_shared_id":-1},"updated":"2023-05-15T13:38:43.474841+00:00"}