STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE β-LACTAMS BY THE REACTION OF CHIRAL IMINES DERIVED FROM ERYTHRO-2-AMINO-1,2-DIPHENYLETHANOL WITH ESTER ENOLATES

Hashimoto, Yukihiko; Ogasawara, Tsuneo; Hayashi, Minoru; Saigo, Kazuhiko

doi:10.3987/COM-99-S95

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STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE β-LACTAMS BY THE REACTION OF CHIRAL IMINES DERIVED FROM ERYTHRO-2-AMINO-1,2-DIPHENYLETHANOL WITH ESTER ENOLATES

http://hdl.handle.net/10173/966

名前 / ファイル	ライセンス	アクション
Heterocycles_52_3_1001.pdf (1.6 MB)

Item type

学術雑誌論文 / Journal Article(1)

公開日

2013-03-29

タイトル

STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE β-LACTAMS BY THE REACTION OF CHIRAL IMINES DERIVED FROM ERYTHRO-2-AMINO-1,2-DIPHENYLETHANOL WITH ESTER ENOLATES

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eng

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資源タイプ識別子

http://purl.org/coar/resource_type/c_6501

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journal article

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抄録

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Abstract

内容記述

Chiral imines, derived from (1S,2R)-2-methoxy-1,2-diphenylethyl-amine and aromatic aldehydes, reacted with ester enolates prepared from ketene silyl acetals and methyllithium to give β-lactams in good yields with high diastereoselectivity. This method provides a useful and simple route for the construction of optically active β-lactam skeletons.

書誌情報

Heterocycles

巻 52, 号 3, p. 1001-1004, 発行日 1905-06-22

ISSN

収録物識別子タイプ

ISSN

収録物識別子

0385-5414

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2023-05-15 13:42:04.740415

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STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE β-LACTAMS BY THE REACTION OF CHIRAL IMINES DERIVED FROM ERYTHRO-2-AMINO-1,2-DIPHENYLETHANOL WITH ESTER ENOLATES

× Hashimoto, Yukihiko

× Ogasawara, Tsuneo

× Hayashi, Minoru

× Saigo, Kazuhiko

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