| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2016-03-25 |
| タイトル |
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|
タイトル |
Kinetic Resolution of Primary Amines via Enantioselective N-Acylation with Acyl Chlorides in the Presence of Supramolecular Cyclodextrin Nanocapsules |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Asahara, Haruyasu
Kida, Toshiyuki
Iwamoto, Takuya
Hinoue, Tomoaki
Akashi, Mitsuru
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| 抄録 |
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内容記述タイプ |
Abstract |
|
内容記述 |
The non-enzymatic kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides was accomplished for the first time by using the selective sequestration of one enantiomer within a supramolecular cyclodextrin (CD) nanocapsule in nonpolar solvents. In addition, the first example of a crystalline structure for an inclusion complex between an acyl chloride and a CD derivative is reported. |
| 書誌情報 |
Tetrahedron
巻 70,
号 2,
p. 197-203,
発行日 2014
|
| DOI |
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関連タイプ |
isVersionOf |
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識別子タイプ |
DOI |
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|
関連識別子 |
10.1016/j.tet.2013.11.097 |
| 著者版フラグ |
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|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
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|
出版者 |
Elsevier Ltd. |
27-44.pdf (524.1 kB)
