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The Pseudo-Intramolecular Process: A Novel Synthetic Method for Functionalized Heterocyclic Compounds
http://hdl.handle.net/10173/1344
http://hdl.handle.net/10173/1344f29ea498-9a9f-422a-ad49-a1480484c061
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
27-13.pdf (1.4 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||
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| 公開日 | 2016-03-25 | |||||||
| タイトル | ||||||||
| タイトル | The Pseudo-Intramolecular Process: A Novel Synthetic Method for Functionalized Heterocyclic Compounds | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| 著者 |
Nishiwaki, Nagatoshi
× Nishiwaki, Nagatoshi
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| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | A pseudo-intramolecular process has been developed. Compounds having both an acidic hydrogen and a functionality serve as substrates in the present method, and immediately form an ammonium salt after the addition of an amine. When the amine is liberated under mild equilibrium conditions, both the nucleophilic amine and the electrophilic substrate are in proximity and efficiently react under mild reaction conditions. Although the reaction actually concerns an intermolecular process, it proceeds as if it were an intramolecular process. Thus, this method forms a novel procedure for synthesizing polyfunctionalized compounds that are not easily available via alternative methods. | |||||||
| 書誌情報 |
Heterocycles 巻 87, 号 5, p. 967-990, 発行日 2013 |
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| DOI | ||||||||
| 関連タイプ | isIdenticalTo | |||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | 10.3987/REV-13-765 | |||||||
| 著者版フラグ | ||||||||
| 出版タイプ | VoR | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||
| 出版者 | ||||||||
| 出版者 | Japan Institute of Heterocyclic Chemistry | |||||||
