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  1. 学術雑誌論文

The Pseudo-Intramolecular Process: A Novel Synthetic Method for Functionalized Heterocyclic Compounds

http://hdl.handle.net/10173/1344
http://hdl.handle.net/10173/1344
f29ea498-9a9f-422a-ad49-a1480484c061
名前 / ファイル ライセンス アクション
27-13.pdf 27-13.pdf (1.4 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-03-25
タイトル
タイトル The Pseudo-Intramolecular Process: A Novel Synthetic Method for Functionalized Heterocyclic Compounds
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Nishiwaki, Nagatoshi

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Nishiwaki, Nagatoshi

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内容記述タイプ Abstract
内容記述 A pseudo-intramolecular process has been developed. Compounds having both an acidic hydrogen and a functionality serve as substrates in the present method, and immediately form an ammonium salt after the addition of an amine. When the amine is liberated under mild equilibrium conditions, both the nucleophilic amine and the electrophilic substrate are in proximity and efficiently react under mild reaction conditions. Although the reaction actually concerns an intermolecular process, it proceeds as if it were an intramolecular process. Thus, this method forms a novel procedure for synthesizing polyfunctionalized compounds that are not easily available via alternative methods.
書誌情報 Heterocycles

巻 87, 号 5, p. 967-990, 発行日 2013
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 10.3987/REV-13-765
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
出版者
出版者 Japan Institute of Heterocyclic Chemistry
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