{"_buckets": {"deposit": "439c5654-8970-413e-a997-d58d891c405a"}, "_deposit": {"created_by": 2, "id": "238", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "238"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000238", "sets": ["5"]}, "author_link": ["987", "984", "985", "986"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2006", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "Part. 3", "bibliographicPageEnd": "o138", "bibliographicPageStart": "o136", "bibliographicVolumeNumber": "C62", "bibliographic_titles": [{"bibliographic_title": "Acta Crystallographica Section C"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The crystal structures of the thermally equilibrated two conformational isomers of the title epoxide, spiro[10,11-dihydro-5H-dibenzo[a,d]cycloheptene-5,8’-1’,5’-dimethyl-4’-oxa-tricyclo[5.1.0.0\u003c^3’,5’\u003e]octane-2’,6’-dione] (C_23H_\u003c20\u003eO_3), have been determined by X-ray diffraction. The tricyclicdione skeleton takes the anti-structure of oxirane and cyclopropane rings with respect to the conjunct quinone frame. The major isomer (IIb) has a fairly twisted boat form of the spiro-linked 10,11-dihydro-5H-dibenzo[a,d]cycloheptene ring folding opposite to the adjoining cyclopropane CH_3-substituent, whereas the minor isomer (IIa) has almost ideal twist-boat form of the seven-membered ring inversely folding to the side of relevant CH_3 group. The conformational structures of these isomers have been compared with those of the corresponding isomers of unepoxidized homobenzoquinone.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "International Union of Crystallographers"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1107/S0108270106002800", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "International Union of Crystallographers, H. Asahara, T. Koizumi, E. Mochizuki and T. Oshima, Acta Crystallographica Section C, C62(Part. 3), 2006, p.o136-138"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "ASAHARA, HARUYASU"}], "nameIdentifiers": [{"nameIdentifier": "984", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "KOIZUMI, TAKUYA"}], "nameIdentifiers": [{"nameIdentifier": "985", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "MOCHIZUKI, EIKO"}], "nameIdentifiers": [{"nameIdentifier": "986", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "OSHIMA, TAKUMI"}], "nameIdentifiers": [{"nameIdentifier": "987", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "27-38.pdf", "filesize": [{"value": "247.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 247800.0, "url": {"label": "27-38.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/238/files/27-38.pdf"}, "version_id": "3838a211-6bb1-4a81-a225-dc3b25c7b737"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Thermally Equilibrated Two Conformers of 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene Spiro-linked Homobenzoquinone Epoxide", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Thermally Equilibrated Two Conformers of 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene Spiro-linked Homobenzoquinone Epoxide"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1360", "pubdate": {"attribute_name": "公開日", "attribute_value": "2016-03-25"}, "publish_date": "2016-03-25", "publish_status": "0", "recid": "238", "relation": {}, "relation_version_is_last": true, "title": ["Thermally Equilibrated Two Conformers of 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene Spiro-linked Homobenzoquinone Epoxide"], "weko_shared_id": -1}