{"_buckets": {"deposit": "6035bc3d-9b51-4852-a63f-da187038dec7"}, "_deposit": {"created_by": 2, "id": "248", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "248"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000248", "sets": ["5"]}, "author_link": ["1023", "1022", "1024", "1026", "1020", "1021", "1027", "1025"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2011", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "19", "bibliographicPageEnd": "6754", "bibliographicPageStart": "6750", "bibliographicVolumeNumber": "9", "bibliographic_titles": [{"bibliographic_title": "Organic \u0026 Biomolecular Chemistry"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A carbamoyl-substituted nitrile oxide was generated upon treatment of easily available 2-methyl-4-nitro-3-isoxazolin-5(2H)-one with THF (not dried); the reaction proceeded efficiently even in the absence of any special reagents and reaction conditions. The nitrile oxide caused 1,3-dipolar cycloaddition with common aliphatic nitriles or electron-rich aromatic nitriles to afford 3-functionalized 1,2,4-oxadiazoles, which are expected to serve as precursors for the preparation of a variety of functional materials by the chemical transformation of the carbamoyl group. While conventional preparative methods for 1,2,4-oxadiazoles involve the cycloaddition of an electron-rich nitrile oxide with an electron-deficient nitrile or a nitrile activated by a Lewis acid, our method employs the complementary combination of an electron-rich nitrile and an electron-deficient nitrile oxide- the inverse electron-demand 1,3-cycloaddition. The DFT calculations using B3LYP 6-31G* supported the abovementioned inverse reactivity, and also suggested the presence of an accelerating effect by the carbamoyl group as a result of hydrogen bond formation with a dipolarophilic nitrile.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1039/C1OB05682D", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_15": {"attribute_name": "権利（URI）", "attribute_value_mlt": [{"subitem_rights": "http://pubs.rsc.org/en/Content/ArticleLanding/2011/OB/c1ob05682d#!divAbstract | http://pubs.rsc.org/en/Content/ArticleLanding/2011/OB/c1ob05682d#!divAbstract"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "1020", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kobiro, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "1021", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirao, Shotaro"}], "nameIdentifiers": [{"nameIdentifier": "1022", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sawayama, Jun"}], "nameIdentifiers": [{"nameIdentifier": "1023", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saigo, Kazuhiko"}], "nameIdentifiers": [{"nameIdentifier": "1024", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ise, Yumiko"}], "nameIdentifiers": [{"nameIdentifier": "1025", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okajima, Yoshikazu"}], "nameIdentifiers": [{"nameIdentifier": "1026", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ariga, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "1027", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "27-18.pdf", "filesize": [{"value": "215.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 215300.0, "url": {"label": "27-18.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/248/files/27-18.pdf"}, "version_id": "fb9ffc30-6914-4703-9821-a2b365fc32b4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1370", "pubdate": {"attribute_name": "公開日", "attribute_value": "2016-03-25"}, "publish_date": "2016-03-25", "publish_status": "0", "recid": "248", "relation": {}, "relation_version_is_last": true, "title": ["Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles"], "weko_shared_id": -1}