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Unique Catalytic Effect of a Cyclodextrin Host on Photodimerization of Coumarin in Nonpolar Solvents
http://hdl.handle.net/10173/1380
http://hdl.handle.net/10173/1380c039593d-eaa5-4a76-aa08-1ac74f4c234b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
27-43.pdf (395.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2016-03-25 | |||||
| タイトル | ||||||
| タイトル | Unique Catalytic Effect of a Cyclodextrin Host on Photodimerization of Coumarin in Nonpolar Solvents | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Asahara, Haruyasu
× Asahara, Haruyasu× Iwamoto, Takuya× Kida, Toshiyuki× Akashi, Mitsuru |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Heptakis(6-O-tert-butyldimethylsilyl)-β-cyclodextrin (TBDMS-β-CD) formed inclusion complexes with coumarin in benzene and cyclohexane. The inclusion mode of coumarin within the TBDMS-β-CD cavity was different between these solvents. Photodimerization of coumarin in the solvents was remarkably accelerated by the inclusion within the TBDMS-β-CD cavity. In particular, the largest rate increase was observed when 1.0 equivalent of TBDMS-b-CD was added to coumarin. | |||||
| 書誌情報 |
Tetrahedron Letters 巻 54, 号 7, p. 688-691, 発行日 2013 |
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| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.tetlet.2012.12.006 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Elsevier Ltd. | |||||
