| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2016-03-25 |
| タイトル |
|
|
タイトル |
Unique Catalytic Effect of a Cyclodextrin Host on Photodimerization of Coumarin in Nonpolar Solvents |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Asahara, Haruyasu
Iwamoto, Takuya
Kida, Toshiyuki
Akashi, Mitsuru
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Heptakis(6-O-tert-butyldimethylsilyl)-β-cyclodextrin (TBDMS-β-CD) formed inclusion complexes with coumarin in benzene and cyclohexane. The inclusion mode of coumarin within the TBDMS-β-CD cavity was different between these solvents. Photodimerization of coumarin in the solvents was remarkably accelerated by the inclusion within the TBDMS-β-CD cavity. In particular, the largest rate increase was observed when 1.0 equivalent of TBDMS-b-CD was added to coumarin. |
| 書誌情報 |
Tetrahedron Letters
巻 54,
号 7,
p. 688-691,
発行日 2013
|
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.tetlet.2012.12.006 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
Elsevier Ltd. |
27-43.pdf (395.3 kB)
