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  1. 学術雑誌論文

Electron diffraction study of the sillenites Bi_<12>SiO_<20>, Bi_<25>FeO_<39> and Bi_<25>InO_<39> : Evidence of short-range ordering of oxygen-vacancies in the trivalent sillenites

http://hdl.handle.net/10173/1450
http://hdl.handle.net/10173/1450
18a88118-19ce-4252-b7d0-a4cff906e445
名前 / ファイル ライセンス アクション
28-22.pdf 28-22.pdf (1.8 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-03-24
タイトル
タイトル Electron diffraction study of the sillenites Bi_<12>SiO_<20>, Bi_<25>FeO_<39> and Bi_<25>InO_<39> : Evidence of short-range ordering of oxygen-vacancies in the trivalent sillenites
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Scurti, Craig A.

× Scurti, Craig A.

WEKO 1141

Scurti, Craig A.

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Auvray, Nicolas

× Auvray, Nicolas

WEKO 1142

Auvray, Nicolas

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Lufaso, Michael W.

× Lufaso, Michael W.

WEKO 1143

Lufaso, Michael W.

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Takeda, Seiji

× Takeda, Seiji

WEKO 1144

Takeda, Seiji

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Kohno, Hideo

× Kohno, Hideo

WEKO 1145

Kohno, Hideo

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Arenas, D. J.

× Arenas, D. J.

WEKO 1146

Arenas, D. J.

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抄録
内容記述タイプ Abstract
内容記述 We present an electron diffraction study of three sillenites, Bi_<12>SiO_<20>, Bi_<25>FeO_<39>, and Bi_<25>InO_<39> synthesized using the solid-state method. We explore a hypothesis, inspired by optical studies in the literature, that suggests that trivalent sillenites have additional disorder not present in the tetravalent compounds. Electron diffraction patterns of Bi_<25>FeO_<39> and Bi_<25>InO_<39> show streaks that confirm deviations from the ideal sillenite structure. Multi-slice simulations of electron-diffraction patterns are presented for different perturbations to the sillenite structure - partial substitution of the M site by Bi^<3+>, random and ordered oxygen-vacancies, and a frozen-phonon model. Although comparison of experimental data to simulations cannot be conclusive, we consider the streaks as evidence of short-range ordered oxygen-vacancies.
書誌情報 AIP Advances

巻 4, 号 8, p. 087125-1-087125-10, 発行日 2014-08
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 10.1063/1.4893341
権利(URI)
権利情報 https://creativecommons.org/licenses/by/3.0/ | https://creativecommons.org/licenses/by/3.0/
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
出版者
出版者 AIP Publishing
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