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Synthetic versatility of nanoparticles: A new, rapid, one-pot, single-step synthetic approach to spherical mesoporous (metal) oxide nanoparticles using supercritical alcohols
http://hdl.handle.net/10173/1474
http://hdl.handle.net/10173/14741de141e3-d088-4524-a26c-fe8b85546529
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
28-38.pdf (5.3 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-03-24 | |||||
| タイトル | ||||||
| タイトル | Synthetic versatility of nanoparticles: A new, rapid, one-pot, single-step synthetic approach to spherical mesoporous (metal) oxide nanoparticles using supercritical alcohols | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | mesoporous nanoparticles | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | NMS-IX | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | one-pot single-step synthesis | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | supercritical alcohols | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Wang, Pengyu
× Wang, Pengyu× Kobiro, Kazuya |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A simple, rapid (10 min), one-pot, single-step method for the preparation of solid and hollow spherical porous TiO_2 nanoparticles with large surface areas (100-211 m^2/g) was developed in supercritical alcohols using carboxylic acids as organic additives. The shell thickness of the hollow TiO_2 nanoparticles (20-280 nm) was controlled by adjusting the heating rate (2.0-10.0 °C/min). The preparation of different spherical porous metal oxide nanoparticles, including CeO_2, SiO_2, TiO_2, ZrO_2, and ZnO, demonstrated the versatility of the synthetic approach. In addition, several rare earth-doped spherical mesoporous metal oxide nanoparticles, including CeO_2:Er, CeO_2:Er,Yb, ZrO_2:Er, and TiO_2:Er, which exhibit energy upconversion emission, were successfully prepared using this one-pot, single-step, supercritical methanol method. The obtained spherical mesoporous CeO_2:Er and CeO_2:Er,Yb nanoparticles emit green light upon excitation, even when irradiated with a low-power IR laser (980 nm, 10 mW) without calcination. Several other (metal) elements were also easily doped into spherical, mesoporous TiO_2 nanoparticles, such as Eu, Ce, Yb, Fe, and N, using a similar procedure. Furthermore, the spherical mesoporous TiO_2 nanoparticles were successfully applied as a new material for the transport of DNA via biolistic bombardment. | |||||
| 書誌情報 |
Pure and Applied Chemistry : The Scientific Journal of IUPAC 巻 86, 号 5, p. 785-800, 発行日 2014-05 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0033-4545 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1515/pac-2013-1117 | |||||
| 権利（URI） | ||||||
| 権利情報 | http://dx.doi.org/10.1515/pac-2013-1117 | http://dx.doi.org/10.1515/pac-2013-1117 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | De Gruyter | |||||
