| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-03-24 |
| タイトル |
|
|
タイトル |
Facilitation of the reduction of Pd(II) by the glass surface : Development of a glass-supported palladium catalyst |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Supported Catalyst |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Glass |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Nanoparticles |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Palladium |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Hydroxy Group |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Nishiwaki, Nagatoshi
Mori, Yasuyuki
Fukuoka, Erina
Asahara, Haruyasu
Hirao, Shotaro
Sawayama, Jun
Saigo, Kazuhiko
Konishi, Tomoya
Shimoda, Masahiko
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
A glass-supported palladium catalyst was developed. The catalyst could be used repeatedly (12 times) with a low catalytic loading (0.05 mol%) for the Heck reaction with a turnover number of 45 000, and no special treatment was necessary before catalyst reuse. The catalytic activity was maintained even after the catalyst was left to stand in air for one month. Furthermore, it was found that the glass surface assisted the adsorption and reduction of the Pd(II) species, through which catalytically active Pd(0) nanoparticles were formed and stabilized. |
| 書誌情報 |
Chemical Physics Letters
巻 608,
p. 340-343,
発行日 2014-07
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0009-2614 |
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.cplett.2014.06.005 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
Elsevier B.V. |
28-13.pdf (2.1 MB)
