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Synthesis and characterization of (Pb, Cu)Sr2(RE, Ca)Cu2Oz (z ≈ 7; RE: Sm, Eu or Gd)
http://hdl.handle.net/10173/583
http://hdl.handle.net/10173/5835655186a-27b2-46e0-a587-3609618b9e6e
名前 / ファイル | ライセンス | アクション |
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PC_468_15-20_1166.pdf (1.5 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2010-10-18 | |||||
タイトル | ||||||
タイトル | Synthesis and characterization of (Pb, Cu)Sr2(RE, Ca)Cu2Oz (z ≈ 7; RE: Sm, Eu or Gd) | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | (Pb, Cu)-“1-2-1-2” | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Chemical composition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Single phase | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Maeda, T
× Maeda, T× Mizobuchi, T× Nagayama, M× Takeuchi, K× Kamakura, M× Nishimori, Y |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | By replacing Y with several kinds of rare-earth elements (RE’s), new members of high-temperature superconductor related cuprates, (Pb, Cu)Sr2(RE, Ca)Cu2Oz (z ≈ 7, RE: Sm, Eu and Gd), are successfully prepared in a single-phase form. Chemical formula of these compounds proves to be (Pb(1+x)/2Cu(1−x)/2)Sr2(RE1−xCax)Cu2Oz, which is completely same as that of (Pb, Cu)Sr2(Y, Ca)Cu2Oz. Single phase samples are obtained for x = 0–0.5 in the cases of RE = Sm and Eu while in the case of RE = Gd, those are obtained for x values up to 0.4. Solubility of Ca in the RE site varies in accordance with RE species and seems to strongly depend on its ionic radius, i.e., large RE3+ results in large solubility. In addition, formation process of the present compounds is discussed based on the results of X-ray diffractometry, differential thermal analysis and scanning electron microscopy. | |||||
書誌情報 |
Physica C: Superconductivity 巻 468, 号 15-20, p. 1166-1168, 発行日 2008-09 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0921-4534 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11536733 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.physc.2008.05.024 | |||||
権利 | ||||||
権利情報 | (c)2008 Elsevier B.V. | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier |