{"_buckets": {"deposit": "aed7cb46-2b78-41a3-8954-04fdc5c3ef11"}, "_deposit": {"created_by": 2, "id": "164", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "164"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000164", "sets": ["5"]}, "author_link": ["619", "618", "617"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2005-12-12", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "50", "bibliographicPageEnd": "8760", "bibliographicPageStart": "8757", "bibliographicVolumeNumber": "46", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron Letters"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Fourteen isomers of bis(formylmethano)C60 were isolated and characterized. A mixture of the bisadducts was obtained by the reaction of C60 with an α-formylsulfonium ylide, and then separated into fifteen fractions by preparative HPLC, preparative TLC, and recycling preparative HPLC. Fourteen of fifteen fractions were found to consist of a single isomer, respectively, which were assigned to the trans-2 (3 diastereo-isomers), trans-3 (3 diastereo-isomers), trans-4 (3 diastereo-isomers), equarorial (2 diastereo-isomers), and cis-2 (3 diastereo-isomers) bisadducts by the comparison of their UV/vis spectra with those of the bisadducts obtained by the Bingel-Hirsch reaction. The 1H- and 13C-NMR analysis, the transformation of the formyl groups, and the dipole moment calculation clarified the stereochemistry of the subsitutents on the two cyclopropane bridge-head carbons (in/in, in/out, and out/out)", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.tetlet.2005.10.027", "subitem_relation_type_select": "DOI"}}]}, "item_2_relation_44": {"attribute_name": "関係URI", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "http://www.sciencedirect.com/science/journal/00404039"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.sciencedirect.com/science/journal/00404039", "subitem_relation_type_select": "URI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© 2005 Elsevier Ltd. All rights reserved."}]}, "item_2_source_id_11": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00861801@@@AA11539822", "subitem_source_identifier_type": "NCID"}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0040-4039", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Ito, Hiroshi"}], "nameIdentifiers": [{"nameIdentifier": "617", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishida, Yasuhiro"}], "nameIdentifiers": [{"nameIdentifier": "618", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saigo, Kazuhiko"}], "nameIdentifiers": [{"nameIdentifier": "619", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "TetL_46_50_8757.pdf", "filesize": [{"value": "559.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 559600.0, "url": {"label": "TetL_46_50_8757.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/164/files/TetL_46_50_8757.pdf"}, "version_id": "bbb826ed-107e-423d-91d7-bb39f5809d48"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "bifunctionalization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "diastereo-isomer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "α-formylsulfonium ylide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "fullerene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "regio-isomer", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/784", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-01-28"}, "publish_date": "2012-01-28", "publish_status": "0", "recid": "164", "relation": {}, "relation_version_is_last": true, "title": ["Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends"], "weko_shared_id": -1}