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  1. 学術雑誌論文

Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends

http://hdl.handle.net/10173/784
http://hdl.handle.net/10173/784
b0da7b28-f401-46dd-a2f9-8efd66acee88
名前 / ファイル ライセンス アクション
TetL_46_50_8757.pdf TetL_46_50_8757.pdf (559.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2012-01-28
タイトル
タイトル Preparation and identification of bis(formylmethano)[60]fullerene isomers: the first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends
言語
言語 eng
キーワード
主題Scheme Other
主題 bifunctionalization
キーワード
主題Scheme Other
主題 diastereo-isomer
キーワード
主題Scheme Other
主題 α-formylsulfonium ylide
キーワード
主題Scheme Other
主題 fullerene
キーワード
主題Scheme Other
主題 regio-isomer
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Ito, Hiroshi

× Ito, Hiroshi

WEKO 617

Ito, Hiroshi

Search repository
Ishida, Yasuhiro

× Ishida, Yasuhiro

WEKO 618

Ishida, Yasuhiro

Search repository
Saigo, Kazuhiko

× Saigo, Kazuhiko

WEKO 619

Saigo, Kazuhiko

Search repository
抄録
内容記述タイプ Abstract
内容記述 Fourteen isomers of bis(formylmethano)C60 were isolated and characterized. A mixture of the bisadducts was obtained by the reaction of C60 with an α-formylsulfonium ylide, and then separated into fifteen fractions by preparative HPLC, preparative TLC, and recycling preparative HPLC. Fourteen of fifteen fractions were found to consist of a single isomer, respectively, which were assigned to the trans-2 (3 diastereo-isomers), trans-3 (3 diastereo-isomers), trans-4 (3 diastereo-isomers), equarorial (2 diastereo-isomers), and cis-2 (3 diastereo-isomers) bisadducts by the comparison of their UV/vis spectra with those of the bisadducts obtained by the Bingel-Hirsch reaction. The 1H- and 13C-NMR analysis, the transformation of the formyl groups, and the dipole moment calculation clarified the stereochemistry of the subsitutents on the two cyclopropane bridge-head carbons (in/in, in/out, and out/out)
書誌情報 Tetrahedron Letters

巻 46, 号 50, p. 8757-8760, 発行日 2005-12-12
ISSN
収録物識別子タイプ ISSN
収録物識別子 0040-4039
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00861801@@@AA11539822
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 10.1016/j.tetlet.2005.10.027
権利
権利情報 © 2005 Elsevier Ltd. All rights reserved.
著者版フラグ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
出版者
出版者 Elsevier
関係URI
識別子タイプ URI
関連識別子 http://www.sciencedirect.com/science/journal/00404039
関連名称 http://www.sciencedirect.com/science/journal/00404039
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