{"_buckets": {"deposit": "e6888357-851e-4bac-9658-89e86ccc329a"}, "_deposit": {"created_by": 2, "id": "191", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "191"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000191", "sets": ["5"]}, "author_link": ["757", "759", "756", "755", "754", "760", "758", "753", "752"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012-02", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "183", "bibliographicPageStart": "178", "bibliographicVolumeNumber": "62", "bibliographic_titles": [{"bibliographic_title": "The Journal of Supercritical Fluids"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Simple treatment of conjugated all E-dienal, (2E,4E)-hexa-2,4-dienal, in subcritical water afforded an intramolecular redox product, non-conjugated Z-enoic acid, (Z)-hex-3-enoic acid, in 42% yield without the usage of a metal catalyst in one-step under the conditions of 250 ℃, 10 min, and 0.35 g mL^\u003c-1\u003e water amount. Similar treatment of the dienal in superheated benzyl alcohol produced corresponding ester, benzyl (Z)-hex-3-enoate, in 34% yield under the conditions of 300 °C, 30 min, and 0.5 g mL^\u003c-1\u003e benzyl alcohol amount. The obtained (Z)-hex-3-enoic acid was transformed to cis-β-hydroxy-γ-ethyl-γ-lactone in 90% yield by hydrogen peroxide at 60 °C for one day under solvent-free conditions.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.supflu.2011.10.022", "subitem_relation_type_select": "DOI"}}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0896-8446", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Chen, Xin"}], "nameIdentifiers": [{"nameIdentifier": "752", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sumoto, Kana"}], "nameIdentifiers": [{"nameIdentifier": "753", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Mitani, Sotatsu"}], "nameIdentifiers": [{"nameIdentifier": "754", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamagami, Tetsuya"}], "nameIdentifiers": [{"nameIdentifier": "755", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yokoyama, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "756", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Wang, Pengyu"}], "nameIdentifiers": [{"nameIdentifier": "757", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirao, Shotaro"}], "nameIdentifiers": [{"nameIdentifier": "758", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "759", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kobiro, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "760", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "JSF_62_178.pdf", "filesize": [{"value": "238.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 238800.0, "url": {"label": "JSF_62_178.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/191/files/JSF_62_178.pdf"}, "version_id": "3a4748f4-74d0-4639-968b-c7817ff25763"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/962", "pubdate": {"attribute_name": "公開日", "attribute_value": "2013-03-29"}, "publish_date": "2013-03-29", "publish_status": "0", "recid": "191", "relation": {}, "relation_version_is_last": true, "title": ["One-step and Non-catalytic Intramolecular Redox Reactions of Conjugated All E-Dienals to Non-conjugated Z-Enoic Acids in Subcritical Water"], "weko_shared_id": -1}