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Efficient double bond migration of allylbenzenes catalyzed by Pd(OAc)_2-HFIP system with unique substituent effect
http://hdl.handle.net/10173/1337
http://hdl.handle.net/10173/1337b9e58b89-b8df-467e-992d-495a3faf84ba
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
27-14.pdf (98.2 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2016-03-25 | |||||
| タイトル | ||||||
| タイトル | Efficient double bond migration of allylbenzenes catalyzed by Pd(OAc)_2-HFIP system with unique substituent effect | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Nishiwaki, Nagatoshi
× Nishiwaki, Nagatoshi× Kamimura, Ryuichiro× Shono, Kimihiro× Kawakami, Toshihiko× Nakayama, Katsuhisa× Nishino, Kohei× Nakayama, Takayuki× Takahashi, Keisuke× Nakamura, Aki× Hosokawa, Takahiro |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A novel catalyst system of Pd(OAc)2-HFIP induces double-bond migration of allylbenzenes under mild conditions with low catalytic loading to afford 1-propenylbenzenes. The reaction shows unique substituent effect that is highly dependent on the distance of substituents from the allylic moiety. Thus, the reactivity of substrates bearing a methyl group is ordered in para > meta > ortho, whereas it is entirely reversed as ortho > meta > para for methoxy and chloro substituents. | |||||
| 書誌情報 |
Tetrahedron Letters 巻 51, 号 27, p. 3590-3592, 発行日 2010 |
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| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1016/j.tetlet.2010.05.014 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Elsevier Ltd. | |||||
