| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2016-03-25 |
| タイトル |
|
|
タイトル |
Efficient double bond migration of allylbenzenes catalyzed by Pd(OAc)_2-HFIP system with unique substituent effect |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Nishiwaki, Nagatoshi
Kamimura, Ryuichiro
Shono, Kimihiro
Kawakami, Toshihiko
Nakayama, Katsuhisa
Nishino, Kohei
Nakayama, Takayuki
Takahashi, Keisuke
Nakamura, Aki
Hosokawa, Takahiro
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
A novel catalyst system of Pd(OAc)2-HFIP induces double-bond migration of allylbenzenes under mild conditions with low catalytic loading to afford 1-propenylbenzenes. The reaction shows unique substituent effect that is highly dependent on the distance of substituents from the allylic moiety. Thus, the reactivity of substrates bearing a methyl group is ordered in para > meta > ortho, whereas it is entirely reversed as ortho > meta > para for methoxy and chloro substituents. |
| 書誌情報 |
Tetrahedron Letters
巻 51,
号 27,
p. 3590-3592,
発行日 2010
|
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.tetlet.2010.05.014 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
Elsevier Ltd. |
27-14.pdf (98.2 kB)
