{"_buckets": {"deposit": "a0be8db9-2786-4e33-b1fd-3aac20aba2d5"}, "_deposit": {"created_by": 2, "id": "229", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "229"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000229", "sets": ["5"]}, "author_link": ["916", "911", "917", "913", "908", "918", "922", "914", "909", "915", "921", "923", "910", "920", "912", "919"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2011", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "407", "bibliographicPageStart": "405", "bibliographicVolumeNumber": "8", "bibliographic_titles": [{"bibliographic_title": "Physica Status Solidi (C)"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Organopalladium species ({Pd}) immobilized on an Sterminated GaAs substrate (S/GaAs) effectively catalyzes C-C bond formation in the Mizoroki-Heck reaction with cycle durability. However, the immobilizing mechanism of {Pd} is unknown. In this study, we deposited Pd(OCOCH3)2 on S/GaAs in two different methods, namely dry-physical vapor-deposition and wetchemical deposition, and compared the catalytic activities in the Mizoroki-Heck reaction. Also, S-termination and {Pd}-immobilization on GaAs grains were performed by the wet-chemical method to monitor the change in the surface chemical structure during the preparation process with diffuse reflectance Fourier transform infrared spectroscopy (FT-IR). FT-IR measurements implied that the immobilization of catalytic active {Pd} was related to the OH groups on the S-terminated surface. {Pd}-S/GaAs prepared dryphysically showed poor catalytic activity, because {Pd} was not immobilized under absence of OH groups.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "WILEY-VCH Verlag GmbH"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1002/pssc.201000436", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the accepted version of the following article: Konishi, T., Nishiwaki, N., Toujyou, T., Ishikawa, T., Teraoka, T., Ueta, Y., Kihara, Y., Moritoki, H., Tono, T., Musashi, M., Tada, T., Fujikawa, S., Takahasi, M., Bell, G., Shimoda, M. and Tsukamoto, S. (2011), Surface study of organopalladium molecules on S-terminated GaAs. Phys. Status Solidi C, 8: 405-407, which has been published in final form at http://dx.doi.org/10.1002/pssc.201000436"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Konishi, Tomoya"}], "nameIdentifiers": [{"nameIdentifier": "908", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "909", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toujyou, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "910", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishikawa, Takuma"}], "nameIdentifiers": [{"nameIdentifier": "911", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Teraoka, Teruki"}], "nameIdentifiers": [{"nameIdentifier": "912", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ueta, Yukiko"}], "nameIdentifiers": [{"nameIdentifier": "913", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kihara, Yoshifumi"}], "nameIdentifiers": [{"nameIdentifier": "914", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Moritoki, Hideji"}], "nameIdentifiers": [{"nameIdentifier": "915", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tono, Tatsuo"}], "nameIdentifiers": [{"nameIdentifier": "916", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Musashi, Mio"}], "nameIdentifiers": [{"nameIdentifier": "917", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tada, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "918", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Fujikawa, Seiji"}], "nameIdentifiers": [{"nameIdentifier": "919", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Takahasi, Masamitu"}], "nameIdentifiers": [{"nameIdentifier": "920", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Bell, Gavin"}], "nameIdentifiers": [{"nameIdentifier": "921", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shimoda, Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "922", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tsukamoto, Shiro"}], "nameIdentifiers": [{"nameIdentifier": "923", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "27-15.pdf", "filesize": [{"value": "116.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 116100.0, "url": {"label": "27-15.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/229/files/27-15.pdf"}, "version_id": "b296f9a3-7498-4166-bd25-7c32a4298098"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Surface study of organopalladium molecules on S-terminated GaAs", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Surface study of organopalladium molecules on S-terminated GaAs"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1351", "pubdate": {"attribute_name": "公開日", "attribute_value": "2016-03-25"}, "publish_date": "2016-03-25", "publish_status": "0", "recid": "229", "relation": {}, "relation_version_is_last": true, "title": ["Surface study of organopalladium molecules on S-terminated GaAs"], "weko_shared_id": -1}