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Versatility of One-pot, Single-step Synthetic Approach for Spherical Porous (Metal) Oxide Nanoparticles Using Supercritical Alcohols
http://hdl.handle.net/10173/1361
http://hdl.handle.net/10173/1361169807a5-1f00-4151-aa3e-8c8193d53b02
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27-52c.pdf (3.9 MB)
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27-52b.pdf (1.3 MB)
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27-52a.pdf (174.7 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||||
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| 公開日 | 2016-03-25 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Versatility of One-pot, Single-step Synthetic Approach for Spherical Porous (Metal) Oxide Nanoparticles Using Supercritical Alcohols | |||||||||||||
| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | journal article | |||||||||||||
| 著者 |
Wang, Pengyu
× Wang, Pengyu
× Ueno, Kimiyoshi
× Takigawa, Hikaru
× Kobiro, Kazuya
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| 抄録 | ||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||
| 内容記述 | We developed a rapid, one-pot, single-step synthetic method for preparing spherical porous (metal) oxides, titanium dioxide, silica, zirconium dioxide, cerium dioxide, and zinc oxide with large surface areas in a supercritical alcohol containing formic acid or phthalic acid as organic additive in a very short reaction time (10 min). A new type of hollow TiO_2 nanoparticle was obtained by slowly heating the reaction mixtures. The shell thickness of hollow TiO_2 nanoparticles was controlled by adjusting the heating rate. The method proved highly versatile for synthesizing solid and hollow spherical meso/microporous nanoparticles. The spherical mesoporous TiO_2 nanoparticles photocatalytically degraded methylene blue in water under UV irradiation, and successfully transported DNA under biolistic bombardment. | |||||||||||||
| 書誌情報 |
The Journal of Supercritical Fluids 巻 78, p. 124-131, 発行日 2013 |
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| 関連タイプ | isVersionOf | |||||||||||||
| 識別子タイプ | DOI | |||||||||||||
| 関連識別子 | 10.1016/j.supflu.2013.03.023 | |||||||||||||
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| 出版タイプ | AM | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||
| 出版者 | ||||||||||||||
| 出版者 | Elsevier B.V. | |||||||||||||
