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  1. 学術雑誌論文

Development of variously functionalized nitrile oxides

http://hdl.handle.net/10173/1444
http://hdl.handle.net/10173/1444
4d568b4a-1fd6-4ac7-a626-10e486f3a646
名前 / ファイル ライセンス アクション
28-46.pdf 28-46.pdf (251.6 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-03-24
タイトル
タイトル Development of variously functionalized nitrile oxides
言語
言語 eng
キーワード
主題Scheme Other
主題 acylnitrile oxide
キーワード
主題Scheme Other
主題 amide
キーワード
主題Scheme Other
主題 formylnitrile oxide
キーワード
主題Scheme Other
主題 functionalized nitrile oxide
キーワード
主題Scheme Other
主題 Weinreb amide
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Asahara, Haruyasu

× Asahara, Haruyasu

Asahara, Haruyasu

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Arikiyo, Keita

× Arikiyo, Keita

Arikiyo, Keita

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Nishiwaki, Nagatoshi

× Nishiwaki, Nagatoshi

Nishiwaki, Nagatoshi

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抄録
内容記述タイプ Abstract
内容記述 N-Methylated amides (N,4-dimethylbenzamide and N-methylcyclohexanecarboxamide) were systematically subjected to chemical transformations, namely, N-tosylation followed by nucleophilic substitution. The amide function was converted to the corresponding carboxylic acid, esters, amides, aldehyde, and ketone upon treatment with hydroxide, alkoxide, amine, diisobutylaluminium hydride and Grignard reagent, respectively. In these transformations, N-methyl-N-tosylcarboxamides behave like a Weinreb amide. Similarly, N-methyl-5-phenylisoxazole-3-carboxamide was converted into 3-functionalized isoxazole derivatives. Since the amide was prepared by the cycloaddition reaction of ethynylbenzene and N-methylcarbamoylnitrile oxide, the nitrile oxide served as the equivalent of the nitrile oxides bearing a variety of functional groups such as carboxy, alkoxycarbonyl, carbamoyl, acyl and formyl moieties.
書誌情報 Beilstein Journal of Organic Chemistry

巻 11, p. 1241-1245, 発行日 2015-07
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 10.3762/bjoc.11.138
権利
権利情報 © 2015 Asahara et al; licensee Beilstein-Institut.
権利
権利情報 This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
権利
権利情報 The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
権利(URI)
権利情報 https://creativecommons.org/licenses/by/2.0/ | https://creativecommons.org/licenses/by/2.0/
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
出版者
出版者 Beilstein-Institut
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