{"_buckets": {"deposit": "6288cae0-646c-417f-b44b-ffb3b1b1d7c7"}, "_deposit": {"created_by": 2, "id": "269", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "269"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000269", "sets": ["5"]}, "author_link": ["1155", "1160", "1159", "1156", "1157", "1158"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-06", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "6", "bibliographicPageEnd": "1431", "bibliographicPageStart": "1421", "bibliographicVolumeNumber": "71", "bibliographic_titles": [{"bibliographic_title": "Polymer Bulletin"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Springer Berlin Heidelberg"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1007/s00289-014-1132-3", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "The final publication is available at link.springer.com"}]}, "item_2_rights_15": {"attribute_name": "権利（URI）", "attribute_value_mlt": [{"subitem_rights": "http://dx.doi.org/10.1007/s00289-014-1132-3 | http://dx.doi.org/10.1007/s00289-014-1132-3"}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0170-0839", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Sugimoto, Ryuichi"}], "nameIdentifiers": [{"nameIdentifier": "1155", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kaneko, Hideyuki"}], "nameIdentifiers": [{"nameIdentifier": "1156", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saito, Junji"}], "nameIdentifiers": [{"nameIdentifier": "1157", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawahara, Nobuo"}], "nameIdentifiers": [{"nameIdentifier": "1158", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsuo, Shingo"}], "nameIdentifiers": [{"nameIdentifier": "1159", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Matsugi, Tomoaki"}], "nameIdentifiers": [{"nameIdentifier": "1160", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "28-15.pdf", "filesize": [{"value": "446.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 446300.0, "url": {"label": "28-15.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/269/files/28-15.pdf"}, "version_id": "718637ad-89e9-476c-8877-c7cc39a15197"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Atom transfer radical polymerization (ATRP)", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Functionalization of polymers", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Graft polymers", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Halogenated", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Polyolefin", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1453", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-03-24"}, "publish_date": "2017-03-24", "publish_status": "0", "recid": "269", "relation": {}, "relation_version_is_last": true, "title": ["Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers"], "weko_shared_id": -1}