WEKO3
アイテム
Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers
http://hdl.handle.net/10173/1453
http://hdl.handle.net/10173/14538210e543-ec81-442f-aec2-9ad3a17bc534
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
28-15.pdf (446.3 kB)
|
|
| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-03-24 | |||||
| タイトル | ||||||
| タイトル | Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Atom transfer radical polymerization (ATRP) | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Functionalization of polymers | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Graft polymers | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Halogenated | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Polyolefin | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Sugimoto, Ryuichi
× Sugimoto, Ryuichi× Kaneko, Hideyuki× Saito, Junji× Kawahara, Nobuo× Matsuo, Shingo× Matsugi, Tomoaki |
|||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers. | |||||
| 書誌情報 |
Polymer Bulletin 巻 71, 号 6, p. 1421-1431, 発行日 2014-06 |
|||||
| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0170-0839 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1007/s00289-014-1132-3 | |||||
| 権利 | ||||||
| 権利情報 | The final publication is available at link.springer.com | |||||
| 権利（URI） | ||||||
| 権利情報 | http://dx.doi.org/10.1007/s00289-014-1132-3 | http://dx.doi.org/10.1007/s00289-014-1132-3 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | Springer Berlin Heidelberg | |||||
