| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-03-24 |
| タイトル |
|
|
タイトル |
Controlled radical polymerization with polyolefin macroinitiator : a convenient and versatile approach to polyolefin-based block and graft copolymers |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Atom transfer radical polymerization (ATRP) |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Functionalization of polymers |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Graft polymers |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Halogenated |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Polyolefin |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Sugimoto, Ryuichi
Kaneko, Hideyuki
Saito, Junji
Kawahara, Nobuo
Matsuo, Shingo
Matsugi, Tomoaki
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers. |
| 書誌情報 |
Polymer Bulletin
巻 71,
号 6,
p. 1421-1431,
発行日 2014-06
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0170-0839 |
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1007/s00289-014-1132-3 |
| 権利 |
|
|
権利情報 |
The final publication is available at link.springer.com |
| 権利（URI） |
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|
権利情報 |
http://dx.doi.org/10.1007/s00289-014-1132-3 | http://dx.doi.org/10.1007/s00289-014-1132-3 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
Springer Berlin Heidelberg |
28-15.pdf (446.3 kB)
