| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2017-03-24 |
| タイトル |
|
|
タイトル |
Functionalization of a Pyridine Framework through Intramolecular Reissert-Henze Reaction of N-(Carbamoyloxy)pyridinium Salts and Unexpected Insertion of Ethereal Solvents |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| 著者 |
Asahara, Haruyasu
Kataoka, Asuka
Hirao, Shotaro
Nishiwaki, Nagatoshi
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| 抄録 |
|
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内容記述タイプ |
Abstract |
|
内容記述 |
A new strategy for synthesis of the 2-pyridyl carbamates is reported. This strategy exploits a new intramolecular transformation of an acyloxy group from N-carbamoyloxypyridinium salts (Reissert-Henze-type reaction) as the key step. Addition of a silver salt effectively accelerates the intramolecular attack of the carbonyl oxygen at the 2-position of the pyridine ring. Additionally, a new rearrangement of the acyloxy group, combined with insertion of an ethereal solvent to give pyridine derivatives having a coordinating tether, is reported. |
| 書誌情報 |
European Journal of Organic Chemistry
巻 2015,
号 18,
p. 3994-3999,
発行日 2015-06
|
| ISSN |
|
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
1099-0690 |
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
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|
関連識別子 |
10.1002/ejoc.201500443 |
| 権利 |
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|
権利情報 |
This is the accepted version of the following article: European Journal of Organic Chemistry, 2015(18), 3994-3999, 2015-06, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201500443. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [olabout.wiley.com/WileyCDA/Section/id-820227.html]. |
| 著者版フラグ |
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出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
| 出版者 |
|
|
出版者 |
WILEY-VCH Verlag GmbH |
28-45.pdf (744.3 kB)
