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  1. 学術雑誌論文

Functionalization of a Pyridine Framework through Intramolecular Reissert-Henze Reaction of N-(Carbamoyloxy)pyridinium Salts and Unexpected Insertion of Ethereal Solvents

http://hdl.handle.net/10173/1468
http://hdl.handle.net/10173/1468
5e192e13-34e2-46df-81fb-b96a9410280c
名前 / ファイル ライセンス アクション
28-45.pdf 28-45.pdf (744.3 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2017-03-24
タイトル
タイトル Functionalization of a Pyridine Framework through Intramolecular Reissert-Henze Reaction of N-(Carbamoyloxy)pyridinium Salts and Unexpected Insertion of Ethereal Solvents
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Asahara, Haruyasu

× Asahara, Haruyasu

Asahara, Haruyasu

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Kataoka, Asuka

× Kataoka, Asuka

Kataoka, Asuka

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Hirao, Shotaro

× Hirao, Shotaro

Hirao, Shotaro

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Nishiwaki, Nagatoshi

× Nishiwaki, Nagatoshi

Nishiwaki, Nagatoshi

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抄録
内容記述タイプ Abstract
内容記述 A new strategy for synthesis of the 2-pyridyl carbamates is reported. This strategy exploits a new intramolecular transformation of an acyloxy group from N-carbamoyloxypyridinium salts (Reissert-Henze-type reaction) as the key step. Addition of a silver salt effectively accelerates the intramolecular attack of the carbonyl oxygen at the 2-position of the pyridine ring. Additionally, a new rearrangement of the acyloxy group, combined with insertion of an ethereal solvent to give pyridine derivatives having a coordinating tether, is reported.
書誌情報 European Journal of Organic Chemistry

巻 2015, 号 18, p. 3994-3999, 発行日 2015-06
ISSN
収録物識別子タイプ ISSN
収録物識別子 1099-0690
DOI
関連タイプ isVersionOf
識別子タイプ DOI
関連識別子 10.1002/ejoc.201500443
権利
権利情報 This is the accepted version of the following article: European Journal of Organic Chemistry, 2015(18), 3994-3999, 2015-06, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201500443. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [olabout.wiley.com/WileyCDA/Section/id-820227.html].
著者版フラグ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
出版者
出版者 WILEY-VCH Verlag GmbH
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