{"_buckets": {"deposit": "436d7524-c005-47b7-b080-49983e28a391"}, "_deposit": {"created_by": 2, "id": "293", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "293"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000293", "sets": ["5"]}, "author_link": ["1312", "1310", "1314", "1311", "1313", "1315"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "302", "bibliographicPageStart": "297", "bibliographicVolumeNumber": "3", "bibliographic_titles": [{"bibliographic_title": "Asian Journal of Organic Chemistry"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "2-Arylated-5-nitropyridines were efficiently synthesized by a three-component ring transformation of 3,5-dinitro-2-pyridone with aromatic ketones in the presence of ammonium acetate, in which the dinitropyridone serves as a synthetic equivalent of an unstable nitromalonaldehyde. Although a 2,8-diazabicyclo[3.3.1]non-3-ene derivative was also formed as a byproduct, it was converted into nitropyridines under the reaction conditions, heating in the presence of ammonium acetate. This experimental fact implies that the former compound is a kinetically controlled product and the latter is a thermodynamically controlled product because of the aromatization. This method is applicable to various kinds of aryl and (hetero)aryl ketones to afford the corresponding (hetero)arylated pyridines in good to excellent yields.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "John Wiley \u0026 Sons"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1002/ajoc.201300282", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the accepted version of the following article: Corrigendum: Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone Volume 4, Issue 2, 94, Article first published online: 2 February 2015, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201300282/abstract;jsessionid=660535A8C8D3756DDD98C38F7A495083.f04t03?systemMessage=Pay+per+view+article+purchase%28PPV%29+on+Wiley+Online+Library+will+be+unavailable+on+Saturday+11th+March+from+05%3A00-14%3A00+GMT+%2F+12%3A00-09%3A00+EST+%2F+13%3A00-22%3A00+SGT+for+essential+maintenance.++Apologies+for+the+inconvenience.. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy."}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "2193-5807", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Le, Thi Song"}], "nameIdentifiers": [{"nameIdentifier": "1310", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Asahara, Haruyasu"}], "nameIdentifiers": [{"nameIdentifier": "1311", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kobiro, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "1312", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sugimoto, Ryuichi"}], "nameIdentifiers": [{"nameIdentifier": "1313", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saigo, Kazuhiko"}], "nameIdentifiers": [{"nameIdentifier": "1314", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "1315", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "28-12.pdf", "filesize": [{"value": "422.6 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 422600.0, "url": {"label": "28-12.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/293/files/28-12.pdf"}, "version_id": "1a6c4e21-dd70-4fdc-b58b-7ae22c86f8cf"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Biaryls", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Multicomponent reactions", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nitrogen heterocycles", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Nitropyridines", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Ring transformation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1477", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-03-24"}, "publish_date": "2017-03-24", "publish_status": "0", "recid": "293", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone"], "weko_shared_id": -1}