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Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone
http://hdl.handle.net/10173/1477
http://hdl.handle.net/10173/1477e3738fd9-e84f-4e7f-91ff-11b1badb7e0b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
28-12.pdf (422.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2017-03-24 | |||||
| タイトル | ||||||
| タイトル | Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Biaryls | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Multicomponent reactions | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Nitrogen heterocycles | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Nitropyridines | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | Ring transformation | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Le, Thi Song
× Le, Thi Song× Asahara, Haruyasu× Kobiro, Kazuya× Sugimoto, Ryuichi× Saigo, Kazuhiko× Nishiwaki, Nagatoshi |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | 2-Arylated-5-nitropyridines were efficiently synthesized by a three-component ring transformation of 3,5-dinitro-2-pyridone with aromatic ketones in the presence of ammonium acetate, in which the dinitropyridone serves as a synthetic equivalent of an unstable nitromalonaldehyde. Although a 2,8-diazabicyclo[3.3.1]non-3-ene derivative was also formed as a byproduct, it was converted into nitropyridines under the reaction conditions, heating in the presence of ammonium acetate. This experimental fact implies that the former compound is a kinetically controlled product and the latter is a thermodynamically controlled product because of the aromatization. This method is applicable to various kinds of aryl and (hetero)aryl ketones to afford the corresponding (hetero)arylated pyridines in good to excellent yields. | |||||
| 書誌情報 |
Asian Journal of Organic Chemistry 巻 3, 号 3, p. 297-302, 発行日 2014-03 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 2193-5807 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1002/ajoc.201300282 | |||||
| 権利 | ||||||
| 権利情報 | This is the accepted version of the following article: Corrigendum: Synthesis of 2-Aryl-5-Nitropyridines by Three-Component Ring Transformation of 3,5-Dinitro-2-Pyridone Volume 4, Issue 2, 94, Article first published online: 2 February 2015, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/ajoc.201300282/abstract;jsessionid=660535A8C8D3756DDD98C38F7A495083.f04t03?systemMessage=Pay+per+view+article+purchase%28PPV%29+on+Wiley+Online+Library+will+be+unavailable+on+Saturday+11th+March+from+05%3A00-14%3A00+GMT+%2F+12%3A00-09%3A00+EST+%2F+13%3A00-22%3A00+SGT+for+essential+maintenance.++Apologies+for+the+inconvenience.. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| 出版者 | ||||||
| 出版者 | John Wiley & Sons | |||||
