{"_buckets": {"deposit": "3cbafc32-ec27-44a0-ba0b-dba359398840"}, "_deposit": {"created_by": 2, "id": "294", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "294"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000294", "sets": ["5"]}, "author_link": ["1319", "1317", "1321", "1318", "1320", "1316"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "619", "bibliographicPageStart": "614", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "Chirality"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "An improved method, which is highly reproducible, was developed for the enantioseparation of racemic O-ethyl phenylphosphonothioic acid (1a) with brucine by introducing seeding to a supersaturated solution of the diastereomeric salt mixture. The present method gave both diastereomeric salts in high yields with a diastereomeric ratio of \u003e99.5:0.5 upon choosing the crystallization solvent (MeOH for the (R)-1a salt and MeOH/H_2O for the (S)-1a salt). The enantiopure acid 1a showed a good chirality recognition ability for not only strong bases, such as amines and amino alcohols, but also weakly basic alcohols and was applicable as a solvating agent to the ^1H NMR determination of the enantiomeric excess of chiral amines, amino alcohols, and alcohols, including aliphatic substrates.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "John Wiley \u0026 Sons, Inc."}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1002/chir.22315", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_14": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "This is the peer reviewed version of the following article: Chirality 26:614-619, 2014. © 2014 Wiley Periodicals, Inc., which has been published in final form at http://dx.doi.org/10.1002/chir.22315. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."}]}, "item_2_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1520-636X", "subitem_source_identifier_type": "ISSN"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Matsumoto, Kazushige"}], "nameIdentifiers": [{"nameIdentifier": "1316", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sawayama, Jun"}], "nameIdentifiers": [{"nameIdentifier": "1317", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirao, Shotaro"}], "nameIdentifiers": [{"nameIdentifier": "1318", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "1319", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sugimoto, Ryuichi"}], "nameIdentifiers": [{"nameIdentifier": "1320", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saigo, Kazuhiko"}], "nameIdentifiers": [{"nameIdentifier": "1321", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "28-43.pdf", "filesize": [{"value": "385.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 385300.0, "url": {"label": "28-43.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/294/files/28-43.pdf"}, "version_id": "943dce6e-a0a3-4781-9718-0c69e152cea2"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1478", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-03-24"}, "publish_date": "2017-03-24", "publish_status": "0", "recid": "294", "relation": {}, "relation_version_is_last": true, "title": ["Enantiopure O-Ethyl Phenylphosphonothioic Acid : A Solvating Agent for the Determination of Enantiomeric Excesses"], "weko_shared_id": -1}