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Safe cyano(nitro)methylating reagent—Michael addition of cyano-aci-nitroacetate leading to δ-functionalized α-nitronitriles
http://hdl.handle.net/10173/1485
http://hdl.handle.net/10173/1485f990f64a-4dfc-4441-a09a-a79c3137e138
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-03-24 | |||||
タイトル | ||||||
タイトル | Safe cyano(nitro)methylating reagent—Michael addition of cyano-aci-nitroacetate leading to δ-functionalized α-nitronitriles | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Nitroacetonitrile | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Michael addition | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Pyridine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | [1,8]-Naphthyridine | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Polyfunctionalized compound | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Asahara, Haruyasu
× Asahara, Haruyasu× Muto, Kyo× Nishiwaki, Nagatoshi |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A practical, convenient, and safe cyano(nitro)methylation method was developed, in which cyano-aci-nitroacetate served as a synthetic equivalent of anionic nitroacetonitrile. A control of the single/double Michael additions was achieved, which enabled the synthesis of unsymmetrical double Michael adducts. Moreover, the Michael adducts can be used as precursors of pyridine and naphthyridine frameworks. | |||||
書誌情報 |
Tetrahedron 巻 70, 号 37, p. 6522-6528, 発行日 2014-09 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0040-4020 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tet.2014.07.013 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier Ltd. |