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Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines
http://hdl.handle.net/10173/1490
http://hdl.handle.net/10173/149076c7aab0-d79b-4cb8-84bd-102cb82cbc55
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
28-47.pdf (6.9 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-03-24 | |||||
| タイトル | ||||||
| タイトル | Dual Behavior of Iodine Species in Condensation of Anilines and Vinyl Ethers Affording 2-Methylquinolines | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | 2-methylquinoline | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | iodine-mediated reaction | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | aniline | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | vinyl ether | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | redox reaction | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Le, Song Thi
× Le, Song Thi× Yasuoka, Chisa× Asahara, Haruyasu× Nishiwaki, Nagatoshi |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A metal-free, mild and efficient method for the synthesis of 2-methylquinolines was successfully developed by condensation of anilines with vinyl ethers in the presence of catalytic amount of iodine. Modification of both pyridine and benzene moieties was easily achieved by changing only the vinyl ether and aniline. In this reaction, the iodine species was revealed to show dual behavior; molecular iodine serves as an oxidant, while its reduced form, hydrogen iodide, activates the vinyl ether. The redox reaction between these iodine species enables the use of a catalytic amount of iodine in this synthetic method. | |||||
| 書誌情報 |
Molecules 巻 21, 号 7, p. 827-1-827-11, 発行日 2016-06 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1420-3049 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.3390/molecules21070827 | |||||
| 権利 | ||||||
| 権利情報 | This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0). | |||||
| 権利（URI） | ||||||
| 権利情報 | https://creativecommons.org/licenses/by/4.0/ | https://creativecommons.org/licenses/by/4.0/ | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 出版者 | ||||||
| 出版者 | MDPI | |||||
