| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2013-03-29 |
| タイトル |
|
|
タイトル |
Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Nishiwaki, Nagatoshi
Hirao, Shotaro
Sawayama, Jun
Saigo, Kazuhiko
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Nitromalonaldehyde (NMA-H) is one of useful synthons for synthesizing nitro compounds. However, NMA-H itself cannot be practically employed because of its unstable property. Therefore, sodium salt of NMA-H (NMA-Na) has been used as its synthetic equivalent from old time, and NMA-Na is still important even now albeit several restrictions with regard to safety and treatability. On the other hand, dinitropyridone, nitropyrimidinone and dinitropyrazole can be employed in place of NMA-Na for the same purpose, and furthermore azadienamines, formylnitroenamines and dinitropyrazole also serve as the synthetic equivalents of NMA-H, which are usable in common organic solvents with safety. These reagents condense with dinucleophiles to afford various kinds of nitro compounds. |
| 書誌情報 |
Heterocycles
巻 84,
号 1,
p. 115-134,
発行日 2011-07-28
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0385-5414 |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.3987/REV-11-SR(P)3 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| 出版者 |
|
|
出版者 |
Japan Institute of Heterocyclic Chemistry |
Heterocycles_84_1_115.pdf (1.3 MB)
