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  1. 学術雑誌論文

Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles

http://hdl.handle.net/10173/969
http://hdl.handle.net/10173/969
31f26cbf-28fe-4115-9473-2b3477388cd2
名前 / ファイル ライセンス アクション
Heterocycles_84_1_115.pdf Heterocycles_84_1_115.pdf (1.3 MB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2013-03-29
タイトル
タイトル Practically Usable C3 Building Blocks for the Syntheses of Nitro Heterocycles
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Nishiwaki, Nagatoshi

× Nishiwaki, Nagatoshi

Nishiwaki, Nagatoshi

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Hirao, Shotaro

× Hirao, Shotaro

Hirao, Shotaro

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Sawayama, Jun

× Sawayama, Jun

Sawayama, Jun

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Saigo, Kazuhiko

× Saigo, Kazuhiko

Saigo, Kazuhiko

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内容記述タイプ Abstract
内容記述 Nitromalonaldehyde (NMA-H) is one of useful synthons for synthesizing nitro compounds. However, NMA-H itself cannot be practically employed because of its unstable property. Therefore, sodium salt of NMA-H (NMA-Na) has been used as its synthetic equivalent from old time, and NMA-Na is still important even now albeit several restrictions with regard to safety and treatability. On the other hand, dinitropyridone, nitropyrimidinone and dinitropyrazole can be employed in place of NMA-Na for the same purpose, and furthermore azadienamines, formylnitroenamines and dinitropyrazole also serve as the synthetic equivalents of NMA-H, which are usable in common organic solvents with safety. These reagents condense with dinucleophiles to afford various kinds of nitro compounds.
書誌情報 Heterocycles

巻 84, 号 1, p. 115-134, 発行日 2011-07-28
ISSN
収録物識別子タイプ ISSN
収録物識別子 0385-5414
DOI
関連タイプ isIdenticalTo
識別子タイプ DOI
関連識別子 10.3987/REV-11-SR(P)3
著者版フラグ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
出版者
出版者 Japan Institute of Heterocyclic Chemistry
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