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Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid
http://hdl.handle.net/10173/1328
http://hdl.handle.net/10173/1328f66673c5-95d8-4562-8047-59ee7604e7b0
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-03-25 | |||||
タイトル | ||||||
タイトル | Regioselective electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of fulleroid | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ikuma, Naohiko
× Ikuma, Naohiko× Sumioka, Satoko× Asahara, Haruyasu× Oshima, Takumi |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The mCPBA oxidation of methano-bridged [5,6] open fulleroid 1 anomalously resulted in the selective electrophilic addition at the bridgehead anti-Bredt double bond rather than the usual epoxidation. The mechanistic preference for the unprecedented stepwise addition of mCPBA vs the concerted epoxidation was explained in terms of the notable π-orbital misalignment (>30°) based on the B3LYP/6-31G(d) level calculation. | |||||
書誌情報 |
Tetrahedron Letters 巻 53, 号 28, p. 3581-3584, 発行日 2012 |
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DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.tetlet.2012.05.007 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
出版者 | ||||||
出版者 | Elsevier Ltd. |