{"_buckets": {"deposit": "6b899eb1-9324-42a7-b090-3f29e28ac68a"}, "_deposit": {"created_by": 2, "id": "236", "owners": [2], "pid": {"revision_id": 0, "type": "depid", "value": "236"}, "status": "published"}, "_oai": {"id": "oai:kutarr.kochi-tech.ac.jp:00000236", "sets": ["5"]}, "author_link": ["982", "975", "981", "979", "980", "976", "977", "978"], "item_2_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageEnd": "1991", "bibliographicPageStart": "1987", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "Organic \u0026 Biomolecular Chemistry"}]}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A new protocol for synthesizing different functionalized isoxazoles is provided. Carbamoylnitrile oxide generated from nitroisoxazolone underwent inverse electron-demand 1,3-dipolar cycloaddition with 1,3-dicarbonyl compounds in the presence of magnesium acetate that formed magnesium enolatein situ. Although electron-deficient trifluoroacetoacetate did not undergo this cycloaddition under the same conditions, conversion to sodium enolate furnish the corresponding bis-functionalized trifluoromethylisoxazole. The DFT calculations using B3LYP 6-31G+(d,p) also supported the aforementioned reactivity.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_35": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Royal Society of Chemistry"}]}, "item_2_relation_13": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1039/C2OB06925C", "subitem_relation_type_select": "DOI"}}]}, "item_2_rights_15": {"attribute_name": "権利（URI）", "attribute_value_mlt": [{"subitem_rights": "http://pubs.rsc.org/en/content/articlelanding/2012/ob/c2ob06925c#!divAbstract | http://pubs.rsc.org/en/content/articlelanding/2012/ob/c2ob06925c#!divAbstract"}]}, "item_2_version_type_18": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nishiwaki, Nagatoshi"}], "nameIdentifiers": [{"nameIdentifier": "975", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kobiro, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "976", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hirao, Shotaro"}], "nameIdentifiers": [{"nameIdentifier": "977", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sawayama, Jun"}], "nameIdentifiers": [{"nameIdentifier": "978", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saigo, Kazuhiko"}], "nameIdentifiers": [{"nameIdentifier": "979", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ise, Yumiko"}], "nameIdentifiers": [{"nameIdentifier": "980", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nishizawa, Maho"}], "nameIdentifiers": [{"nameIdentifier": "981", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ariga, Masahiro"}], "nameIdentifiers": [{"nameIdentifier": "982", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-02-13"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "27-21.pdf", "filesize": [{"value": "201.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 201000.0, "url": {"label": "27-21.pdf", "url": "https://kutarr.kochi-tech.ac.jp/record/236/files/27-21.pdf"}, "version_id": "0335252e-91e6-4858-b028-9ed37d6a4ea4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters"}]}, "item_type_id": "2", "owner": "2", "path": ["5"], "permalink_uri": "http://hdl.handle.net/10173/1358", "pubdate": {"attribute_name": "公開日", "attribute_value": "2016-03-25"}, "publish_date": "2016-03-25", "publish_status": "0", "recid": "236", "relation": {}, "relation_version_is_last": true, "title": ["One-step synthesis of differently bis-functionalized isoxazoles by cycloaddition of carbamoylnitrile oxide with β-keto esters"], "weko_shared_id": -1}